In this research we employ a range of multivariate asset models based on Lévy processes to price exotic derivatives. We compare their ability to fit market data and replicate price benchmarks, and evaluate their flexibility in terms of parametrization and dependence structure. We review recent risk-neutral calibration approaches and techniques in the multivariate setting, and provide tools to make well-informed decisions in a practical context. A special focus is given to the ability of the models to capture linear and nonlinear dependence, with implications on their pricing performance. Given the exotic features of the analyzed derivatives, valuation is carried out through Monte Carlo methods.