Key words: breakup/coalescence
IntroductionThe fragmentation of drops and bubbles in sheared or turbulent flows has a number of important applications in engineering and earth science fields. Bubble fragmentation in whitecaps, for example, plays an important role in the size distribution of bubbles created by breaking waves, which contributes to air-sea gas flux, aerosol production, ocean albedo, wave breaking energetics and the generation of underwater ambient noise (Melville 1996;Deane & Stokes 2002). The general principles controlling † Email address for correspondence: cmbazan@ujaen.es 160 C. Martínez-Bazán and others the breakup of drops and bubbles in turbulent flows have been established since the works of Kolmogorov (1949) and Hinze (1955) in the early 1950s, but an exact mathematical description of this fundamental fluid dynamical process has not yet been formulated.Since the seminal works of Kolmogorov (Kolmogorov 1949) and Hinze (Hinze 1955), a number of models for bubble fragmentation have been presented, including the phenomenological fragmentation model of Martínez-Bazán, Montañes & Lasheras (1999a, b) that describes the breakup frequency, g(D 0 ), and probability density function (p.d.f.) of daughter bubbles, f (D; D 0 ), produced by the fragmentation of air bubbles in homogeneous, isotropic turbulence (see Lasheras et al. 2002, for a recent review of bubble fragmentation models).The implementation of some breakup models in the population balance equation may lead to the impression that they do not conserve volume since some of the equations for the bubble-size p.d.f. published in the literature are expressed in terms of bubble diameter instead of volume. Thus, some of the turbulent breakup models are based on phenomenological hypotheses and, although they have been developed under the original principle of conservation of volume, especially the binary models, for convenience they are expressed in terms of the bubble diameter and do not always respect the volume-conservation condition. This issue has been also pointed out by Zaccone et al. (2007), who developed an empirical approach to determine the breakup mechanisms in stirred dispersions and an appropriate physical model for the daughter-drop p.d.f, and reported that many models, with the exception of Coulaloglou & Tavlarides (1977) and Luo & Svensen (1996), do not always preserve volume. In fact, they emphasized that models that do not conserve volume lead to an unphysical evolution of the predicted volume fraction.In this paper, in § 2, we state a simple relation that any volume-conserving fragmentation p.d.f. must satisfy, irrespective of the underlying fragmentation physics, making it a simple matter to determine if a model is volume conserving or not. In particular, in § 3, we review the models described in Lasheras et al. (2002) and establish whether they satisfy the conservation of volume and symmetry conditions, and show that the binary models are volume conserving when the equations for the p.d.f.s are expressed in terms of volume ra...