Abstract:Bin Wang Bin Wang studied organic chemistry at the Institute of Elemento-organic Chemistry, Nankai University, and obtained his Ph.D. in 2007 under the supervision of Prof. Ruyu Chen. In the same year, he joined the College of Pharmacy of Nankai University as Assistant Professor. He became Associate Professor in 2009, and initiated his independent research. Presently, he is Visiting Scholar in the research group of Prof. Henry N.C. Wong at the Chinese University of Hong Kong. Professor Wang's current research … Show more
“…Based on the above results in combination with our previous studies, 12 a plausible mechanism for this oxidative olefination was proposed, as outlined in Fig. 1 .…”
A practical and sustainable metal-, additive-free olefination approach is proposed for the facile synthesis of various N-heteroazaarenes with high regioselectivity from simple methyl-substituted heteroarenes and amines using air as the oxidant.
“…Based on the above results in combination with our previous studies, 12 a plausible mechanism for this oxidative olefination was proposed, as outlined in Fig. 1 .…”
A practical and sustainable metal-, additive-free olefination approach is proposed for the facile synthesis of various N-heteroazaarenes with high regioselectivity from simple methyl-substituted heteroarenes and amines using air as the oxidant.
“…The catalytic utilization of bromine reagents in C–H bond functionalization has been realized through an in situ bromination and followed homolytic cleavage. The present example disclosed a new strategy for radical C–H bond activation, which would be valuable for the development of green and sustainable chemistry …”
An NBS-induced intramolecular cycloaromatization for the synthesis of 10-phenanthrenols from electron-withdrawing group substituted 1-biphenyl-2-ylethanones is described. The in situ generated bromide was designed to act as an initiator for the radical C-H bond activation. An oxidative cross-dehydrogenative coupling reaction of a highly active C-H bond with an inert C-H bond readily occurs under mild conditions without the need for transition metals or strong oxidants.
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