Brilliant triboluminescence in a potential organic–inorganic hybrid ferroelectric: (Ph₃PO)₂MnBr₂

Abstract

A potential organic–inorganic hybrid molecular ferroelectric, (Ph3PO)2MnBr2, exhibits intense triboluminescence at a green wavelength.

Triboluminescence Phenomenon Based on the Metal Complex Compounds—A Short Review

“…Additional data are collected in the Table 4 . Unit cell angles are as follows: α = 65.31(6)°, β = 63.75(5)° γ = 89.72(7)° [ 34 ].…”

Metal ion modulation triggers dielectric double switching and green fluorescence in A2MX4-type compounds

“…[1][2][3][4][5][6][7][8][9][10][11] Based on the above characteristics, these types of materials have potential applications in the fields of sensors, optoelectronic devices, information storage, signal processing, and switches. [12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27] Organic-inorganic hybrid (OIH) materials possess good structural tunability and overcome the disadvantages of conventional inorganic materials such as low flexibility and high cost. Therefore, they are considered as ideal materials for designing multifunctional responsive materials.…”

Manganese(II) Thiocyanate Complexes with Bis(phosphine Oxide) Ligands: Synthesis and Excitation Wavelength‐Dependent Multicolor Luminescence

“…For instance, some of them, e.g. [Mn(Ph 3 PO) 2 Br 2 ], exhibit bright photo‐ and triboluminescence at ambient temperature . The [Mn(DPEPhosO 2 )Hal 2 ] complexes derived from DPEPhos dioxide were claimed as bright photo‐ and triboluminescent .…”

“…Particular interest is devoted to Mn II halide complexes with phosphine oxide ligands , . For instance, some of them, e.g.…”