Bridging Titanium Nitrido Complexes Containing A Linear Ti−N−Ti Core with A Two‐Coordinate Nitrido Ligand
Akira Okumura,
Priyabrata Ghana,
Thomas P. Spaniol
et al.
Abstract:A series of titanium m2‐nitrido complexes supported by the triamidoamine ligand Xy‐N3N (Xy‐N3N = {(3,5‐Me2C6H3)NCH2CH2}3N3–) is reported. The titanium azido complex [(Xy‐N3N)TiN3] (1‐N3), prepared by salt metathesis of the chloride complex [(Xy‐N3N)TiCl] (1‐Cl) with NaN3, reacted with lithium metal or with alkali metal naphthalenides (alkali metal M = Na, K, and Rb) in THF to give the corresponding dinuclear m2‐nitrido complexes M[(Xy‐N3N)Ti=N‐Ti(Xy‐N3N)] (2‐M; M = Li, Na, K, Rb). Single crystal X‐ray diffract… Show more
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