The structure of the superconducting order parameter of LiFeAs is studied by incoherent multiple Andreev reflections effect (IMARE) spectroscopy. The high transparent superconductor–thin normal metal–superconductor (SnS) contacts are created by a planar “break-junction” technique. Below $$T_c \approx 17.5$$
T
c
≈
17.5
K, the obtained I(V) and dI(V)/dV characteristics of SnS junctions show a presence of at least three bulk superconducting order parameters in LiFeAs. We directly determine the magnitudes, characteristic ratios, and temperature dependences of the superconducting gaps and discuss their symmetry.