1992
DOI: 10.1063/1.106553
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Bound exciton luminescence in ZnSe under hydrostatic pressure

Abstract: We report pressure-dependent photoluminescence (PL) measurements on ZnSe single crystals grown by the seeded physical vapor phase transport technique. Two kinds of ZnSe samples, the as-grown and Zn-extracted single crystals were used in this study. The Id1 line is the predominant spectral feature for the as-grown samples and shifts with pressure at a rate of 7.3 meV/kbar. The I3 emission dominates the PL spectra of the Zn-extracted samples and has a pressure coefficient of 6.6 meV/kbar, which is inconsistent w… Show more

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Cited by 15 publications
(6 citation statements)
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“…Though the application of pressure increases the binding energy of a shallow exciton because of an increase in the electron effective mass and a decrease in the dielectric constant, the pressure-induced change of its binding energy is expected to be quite negligible ͑Ͻ1%͒, as is seen by using the effective-mass approximation. 4,8 Therefore, it is reasonable that the pressure dependence of the I 2 line at 9 K should be the same as that of the band gap at 9 K. 7 The magnitude of ␤ for the I 2 line in wurtzite GaN at 9 K determined here is smaller than that for the free electronbound hole ͑FB͒ transition line in zinc-blende GaN ͑Ref. 4͒ ͑Table I͒, while the values of ␣ for both structures are the 2. The dependence of the PL peak energies of the I 2 line ͑᭺ at 9 K, ᭹ at 300 K͒, the ''yellow'' band ͑ᮀ at 9 K, at 300 K͒, and the DAP lines ͑zero phonon ͑ࡗ͒, one phonon ͑᭝͒, and two phonon ͑᭞͒ lines at 9 K͒ as a function of pressure.…”
mentioning
confidence: 69%
“…Though the application of pressure increases the binding energy of a shallow exciton because of an increase in the electron effective mass and a decrease in the dielectric constant, the pressure-induced change of its binding energy is expected to be quite negligible ͑Ͻ1%͒, as is seen by using the effective-mass approximation. 4,8 Therefore, it is reasonable that the pressure dependence of the I 2 line at 9 K should be the same as that of the band gap at 9 K. 7 The magnitude of ␤ for the I 2 line in wurtzite GaN at 9 K determined here is smaller than that for the free electronbound hole ͑FB͒ transition line in zinc-blende GaN ͑Ref. 4͒ ͑Table I͒, while the values of ␣ for both structures are the 2. The dependence of the PL peak energies of the I 2 line ͑᭺ at 9 K, ᭹ at 300 K͒, the ''yellow'' band ͑ᮀ at 9 K, at 300 K͒, and the DAP lines ͑zero phonon ͑ࡗ͒, one phonon ͑᭝͒, and two phonon ͑᭞͒ lines at 9 K͒ as a function of pressure.…”
mentioning
confidence: 69%
“…Energetic position and fast quenching with temperature allow tentative identification of the peaks at 3.3730 and 3.3742 eV as the ionized counterparts of the I 4 and I 5 peaks, respectively. 17,18 A T emission is observed from this EPLD grown sample along with peaks which are likely from LPB A and UPB A recombination. For comparison, the 3.5 K PL spectrum from the EPLD grown sample has been redshifted by 1.5 meV in Fig.…”
Section: Resultsmentioning
confidence: 74%
“…[20][21][22] Although the exact nature of the acceptors is not clear, the defect is usually attributed either to the Zn vacancies or to the substitutional impurities Cu Zn . 21,22 As being reported in the literature, the Zn-vacancies can also appear in the ZnSe films grown by molecular beam epitaxy, especially near the film/substrate interface, with a density depending on the growth conditions. 23,.…”
Section: Photoluminescence Spectramentioning
confidence: 99%