Boron‐Thioketonates: A New Class of S,O‐Chelated Boranes as Acceptors in Optoelectronic Devices

Abstract

Development of new n‐type semiconductors with tunable band gap and dielectric constant has significant implication in dissociating bound charge carrier relevant for demonstrating high performance optoelectronic devices. Boron‐β‐thioketonates (MTDKB), analogues to boron‐β‐diketonates containing a sulfur atom in the framework of β‐diketones were synthesized. Bulk transport measurement exhibited an outstanding bulk electron mobility of ≈0.003 cm2 V−1 s−1, which is among the best values reported till date in these class of semiconducting materials and correspondingly a single junction photo responsivity of upto 6 mA W−1 was obtained. This new family of O,S‐chelated boron compounds exhibited luminescence in the far red/near‐infrared region. The remarkable red shift of 89 nm (fluorescence) observed for 4 a in comparison with analogues boron‐β‐diketonate signifies the importance of sulfur in these molecules. MTDKBs with amine functionality have also been investigated as an ON/OFF fluorescent sensor.

Feasible Synthesis of N, O-Bidentate Difluoroboron Chromo-phores through Direct Functionalization of Quinoxalin-2(1H)-ones with Ketones in One Shot

“…istry and material science owing to their superior photophysical properties, such as high fluorescent quantum yield, tunable structure and emission, as well as robust photo-and chemical stability. [2][3][4][5] Especially in the last decade, a large number of difluoroboron complexes have been explored and applied in fluorescent sensing, laser dyes, organic light-emitting devices, bioconjugates components, bio-imaging, [6][7][8][9][10] and even singlet-oxygen generators for photodynamic therapy. [11,12] According to the difference of the ligands, organic difluoroboron complexes can be categorized into three types: N,N-bidentate type, O,O-bidentate type, and N,O-bidentate type.…”