Abstract:39) TVA, unpublished research on system Ca0-P205-HF-H20. (40) Wall, F. T., Grieger, P. F., Childers, C. W., J. Am. Chem. Soc. 74, 3562 (1952).(41) Wildermann, M., Z. physik. Chem. 66, 445 (1909).
“…Exploratory vegetative tests in this laboratory and elsewhere (7) show that certain glasses will eliminate a boron deficiency condition of a soil. The influence of a slightly reactive glass persists, Boron content of alfalfa remains in the same range for 2 or more years.…”
Section: Literature Citedmentioning
confidence: 75%
“…Boron content of plant tissue was determined by the curcumin method, as described by Dible, Truog, and Berger (6). Procedures followed in determining the compositions of the glasses were ophenanthroline (8) for iron, Versenate titration (4) for calcium and magnesium after separation from manganese by carbamate extraction (5), and ASTM standard methods (7) for other constituents.…”
Section: Methodsmentioning
confidence: 99%
“…Furthermore, toxic levels are not reached in the crop even when the amounts of boron contained in glass applications are (6) Rediske, J. H., U. S. Atomic Energy Comm. HW-42969 (May 7,1956). (7) Slack, A. V., Com. Fertilizer 95, 28-9, 33, 35-7, 39-40 (August 1957).…”
Section: Literature Citedmentioning
confidence: 99%
“…In a greenhouse experiment of the present investigation, six glasses, selected to represent a broad range of reactivity as varied by chemical composition alone, were compared, using borax as a soluble reference material. Basically, the conditions of experimentation were essentially the same as in a previous investigation (7) except for some modification in the method of watering the crop made in an effort to maintain greater uniformity in soil moisture. Alfalfa was grown on a coarse-textured soil to which the test materials had been added.…”
Figure 5. Parkerizing effect on mild steelLeft. Medium coating on specimen exposed to 9.3-29.9-0 solution at 175°F.Center. Heavy coating on specimen exposed to 10-10-10 at 200°F. Right. No coating on specimen exposed to 9.3-29.9-0 at room temperature Table XII. Corrosion of Stainless Steel by Liquid Mixed Fertilizer Corrosion Rate, Test Temp., Mils Penetration per Yr. Grade Conditiona 0 F. Type 430 Type 376
“…Exploratory vegetative tests in this laboratory and elsewhere (7) show that certain glasses will eliminate a boron deficiency condition of a soil. The influence of a slightly reactive glass persists, Boron content of alfalfa remains in the same range for 2 or more years.…”
Section: Literature Citedmentioning
confidence: 75%
“…Boron content of plant tissue was determined by the curcumin method, as described by Dible, Truog, and Berger (6). Procedures followed in determining the compositions of the glasses were ophenanthroline (8) for iron, Versenate titration (4) for calcium and magnesium after separation from manganese by carbamate extraction (5), and ASTM standard methods (7) for other constituents.…”
Section: Methodsmentioning
confidence: 99%
“…Furthermore, toxic levels are not reached in the crop even when the amounts of boron contained in glass applications are (6) Rediske, J. H., U. S. Atomic Energy Comm. HW-42969 (May 7,1956). (7) Slack, A. V., Com. Fertilizer 95, 28-9, 33, 35-7, 39-40 (August 1957).…”
Section: Literature Citedmentioning
confidence: 99%
“…In a greenhouse experiment of the present investigation, six glasses, selected to represent a broad range of reactivity as varied by chemical composition alone, were compared, using borax as a soluble reference material. Basically, the conditions of experimentation were essentially the same as in a previous investigation (7) except for some modification in the method of watering the crop made in an effort to maintain greater uniformity in soil moisture. Alfalfa was grown on a coarse-textured soil to which the test materials had been added.…”
Figure 5. Parkerizing effect on mild steelLeft. Medium coating on specimen exposed to 9.3-29.9-0 solution at 175°F.Center. Heavy coating on specimen exposed to 10-10-10 at 200°F. Right. No coating on specimen exposed to 9.3-29.9-0 at room temperature Table XII. Corrosion of Stainless Steel by Liquid Mixed Fertilizer Corrosion Rate, Test Temp., Mils Penetration per Yr. Grade Conditiona 0 F. Type 430 Type 376
This paper is part of a series of investigations into the reaction rate of acid dissolution of solids
and particularly the influence of particle size distribution. In the case of acid dissolution of raw
phosphate particles, preliminary results show that the reaction rate is significantly affected by
the particle size distribution. In this paper, the dissolution into a 0.3 M H3PO4 solution of one
size fraction 125−200 μm (d
p = 162.5 μm) prepared by sieving has been studied at 25 °C using
a batch method. Experimental data were fitted to an empirical equation of the form m/m
∞ = 1
− e-
kt
, where m is the mass of phosphate dissolved at time t and m
∞ is the final mass of phosphate
dissolved. The dissolution rate constant k was found to be equal to 0.2118 min-1. Variation of
the physical properties of the remaining solid with reaction time was studied. Experimental
methods such as scanning electron microscopy (SEM), mercury porosimetry, argon adsorption/desorption isotherms, and volume displacement using helium for the determination of the true
density were used. As a result, a significant change in the Brunauer−Emmett−Teller surface
area (S
BET) occurred during the reaction. S
BET was 16 m2·g-1 at t = 0 min, it reached a minimum
value of 10 m2·g-1 at 7 min, and it increased again to 24 m2·g-1 at t = 50 min. Moreover, SEM
observations revealed that phosphate particles dissolve beginning from their surface without
any disintegration.
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