“…20 Also, the BP compounds can exist in planer (twodimensional), tubular (one-dimensional), or spherical shapes (zero-dimensional), quite the same as the graphene, carbon nanotubes, and fullerenes, respectively. All structures of BP compounds are prominent as large band-gap semiconductor material having many advanced properties such as promising materials for microelectronic and optoelectronic applications, 21,22 high thermal conductivity 23 hardness, and chemical stability, [23][24][25] a good candidate for application in catalysis. 20,26,27 With respect to both boron and phosphorus elements can form 2D materials, it is engaging to determine, whether the binary compound of boron and phosphorus can form stable clusters, which may display unusual structural and electronic properties better than both boron and phosphorus clusters.…”