Boron Particles Production inNonequilibrium Laser‐Chemical RadicalReactions During the IR MultiphotonDissociation of HCIC=CBCI₂H Molecules

Abstract

The study of IR MPD of HCIC=CBCI2H molecule by CO2.-laser is presented. We provide experimental results showing high degree of fragmentation of this molecule (down to elementary boron) during nonequilibrium laser induced radical bimolecular reactions.

Semiconductive Nanostructures - Materials for Spinelectronics: New Data Bank Requirement

“…The greatest interest is in modes of small particle production providing high dispersion and purity as well as the study of the processes of cluster conception and growth. Established theory and experiment have shown that elementary boron atoms group into an aggregate of icosahedrical form consisting of 12 boron atoms (B 12 ) [23,24]. Usually the boron small particles consist of one or more icosahedrons united in a cluster or various configurations depending on the thermodynamic conditions at formation.…”