Abstract:The alumole Cp3tAlC4Et4 (Cp3t = 1,2,4-tris(tert-butyl)cyclopentadienyl) is reported to be capable of transferring its butadiene moiety to aryl(dihalo)boranes to generate boroles through aluminum-boron exchange. The products feature a rare alkyl-substituted...
N-borylation of a 1,2-azaborinine with boron-doped (anti)aromatic substituents provides access to a range of novel BNB-doped multiply fused heterocycles resulting from the spontaneous or reductive intramolecular C–H activation of a phenyl residue.
N-borylation of a 1,2-azaborinine with boron-doped (anti)aromatic substituents provides access to a range of novel BNB-doped multiply fused heterocycles resulting from the spontaneous or reductive intramolecular C–H activation of a phenyl residue.
Extended conjugation has been introduced into boroles but only on the 2,3- or 4,5-positions of the central BC4 core. In this work we synthesize phenanthrylboroles that also have conjugation on...
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