“…The decrease in R ct can be attributed to the process of activation after cycling. Furthermore, based on eqn (5) and (6), the diffusion coefficient of Li + ( D Li+ ) can be obtained: 66,69,70 D = R 2 T 2 /2 n 4 F 4 σ w 2 A 2 C 2 Z ′ = R + σ w ω -1/2 where R and T represent the gas constant and temperature, respectively. A , C , n , F and σ w are ascribed to the area of the electrode, the concentration of Li + , the number of electrons, Faraday constant, and Warburg coefficient, respectively.…”