2004
DOI: 10.1080/09500340408232495
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Bloch equations and completely positive maps

Abstract: The phenomenological dissipation of the Bloch equations is reexamined in the context of completely positive maps. Such maps occur if the dissipation arises from a reduction of a unitary evolution of a system coupled to a reservoir. In such a case the reduced dynamics for the system alone will always yield completely positive maps of the density operator. We show that, for Markovian Bloch maps, the requirement of complete positivity imposes some Bloch inequalities on the phenomenological damping constants. For … Show more

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Cited by 9 publications
(2 citation statements)
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References 18 publications
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“…Some examples of nonphysical behavior of the full Redfield equation are given in refs 111, 122, 140, and 142. Similar difficulties have been found for the Bloch equations, which describe the nuclear induction of a spin that interacts with a magnetic field 147. The problems associated with the Redfield equations are a consequence of the second-order perturbation theory and the Markovian approximation 140.…”
Section: Coupling With Phonons; Exciton-dephasing and Transportmentioning
confidence: 69%
“…Some examples of nonphysical behavior of the full Redfield equation are given in refs 111, 122, 140, and 142. Similar difficulties have been found for the Bloch equations, which describe the nuclear induction of a spin that interacts with a magnetic field 147. The problems associated with the Redfield equations are a consequence of the second-order perturbation theory and the Markovian approximation 140.…”
Section: Coupling With Phonons; Exciton-dephasing and Transportmentioning
confidence: 69%
“…in order to ensure that the reduced dynamics for the system always leads to completely positive maps of the density matrix [15], i.e., that Tr [ρ 2 S ] ≤ 1 at any time. Thus, although the Bloch equation is mathematically well-defined for any values of T 1 and T 2 , they lose their physical meaning when Eq.…”
Section: The Two Level Systemmentioning
confidence: 99%