Mechanistic models have been developed for particle and vapor deposition on the blades of coal-fired gas turbines. The particle deposition models include the simultaneous contribution of Brownian and turbulent diffusion, thermophoresis, eddy impaction, and inertial impingement. The diffusive mechanisms have been validated against experimental data for low-speed cascade flow and particle-laden flow through pipes. The inertial deposition treatment is shown to collapse to the well-known expression for particle capture in a flow turning around a bend. A method is presented for calculating Na2SO4 and K2SO4 vapor deposition on cooled blades. Scaling laws are formulated for estimating the contribution of boundary layer homogeneous and heterogeneous nucleation mechanisms for highly cooled turbine blades.