“…The area‐specific capacitance is used to evaluate the energy storage properties and is given by Equation . [ 41 ] …”
Section: Resultsmentioning
confidence: 99%
“…The area-specific capacitance is used to evaluate the energy storage properties and is given by Equation 2. [41] C a = It∕ΔU (2) Where C a is the area-specific capacitance (mF cm −2 ), I is the current density (mA cm −2 ), ΔU is the difference in applied voltage (V), and t is the discharge time (s). It is calculated that the C a of the film is 5.3 mF cm −2 at a current density of 0.5 mA cm −2 .…”
Section: Electrochromic and Energy Storage Properties Of P1/p2 Bilaye...mentioning
This work presents a new strategy to achieve highly stable electrochromic devices and bilayer film construction. A novel solution‐processable electrochromic polymer P1‐Boc with quinacridone as the conjugated backbone and t‐Boc as N‐substituted non‐conjugated solubilizing groups is designed. Thermal annealing of P1‐Boc film results in the cleavage of t‐Boc groups and the formation of N─H⋯O═C hydrogen‐bonding crosslinked network, which changes its intrinsic solubility characteristics into a solvent‐resistant P1 film. This film retains the electrochemical behavior and spectroelectrochemistry properties of the original P1‐Boc film. Intriguingly, the electrochromic device based on the P1 film exhibits an ultrafast switching time (0.56/0.80 s at 523 nm) and robust electrochromic stability (retaining 88.4% of the initial optical contrast after 100 000 cycles). The observed cycle lifetime is one of the highest reported for all‐organic electrochromic devices. In addition, a black‐transparent bilayer electrochromic film P1/P2 is developed in which the use of the solvent‐resistant P1 film as the bottom layer avoids interface erosion of the solution‐processable polymer in a multilayer stacking.
“…The area‐specific capacitance is used to evaluate the energy storage properties and is given by Equation . [ 41 ] …”
Section: Resultsmentioning
confidence: 99%
“…The area-specific capacitance is used to evaluate the energy storage properties and is given by Equation 2. [41] C a = It∕ΔU (2) Where C a is the area-specific capacitance (mF cm −2 ), I is the current density (mA cm −2 ), ΔU is the difference in applied voltage (V), and t is the discharge time (s). It is calculated that the C a of the film is 5.3 mF cm −2 at a current density of 0.5 mA cm −2 .…”
Section: Electrochromic and Energy Storage Properties Of P1/p2 Bilaye...mentioning
This work presents a new strategy to achieve highly stable electrochromic devices and bilayer film construction. A novel solution‐processable electrochromic polymer P1‐Boc with quinacridone as the conjugated backbone and t‐Boc as N‐substituted non‐conjugated solubilizing groups is designed. Thermal annealing of P1‐Boc film results in the cleavage of t‐Boc groups and the formation of N─H⋯O═C hydrogen‐bonding crosslinked network, which changes its intrinsic solubility characteristics into a solvent‐resistant P1 film. This film retains the electrochemical behavior and spectroelectrochemistry properties of the original P1‐Boc film. Intriguingly, the electrochromic device based on the P1 film exhibits an ultrafast switching time (0.56/0.80 s at 523 nm) and robust electrochromic stability (retaining 88.4% of the initial optical contrast after 100 000 cycles). The observed cycle lifetime is one of the highest reported for all‐organic electrochromic devices. In addition, a black‐transparent bilayer electrochromic film P1/P2 is developed in which the use of the solvent‐resistant P1 film as the bottom layer avoids interface erosion of the solution‐processable polymer in a multilayer stacking.
“…Electrochemical polymerization is a well-established methodology to prepare polymer film directly on an electrode surface without unmanageable chemical polymerization reactions and complicated purifications. 98,99 Cheng Zhang et al 87 prepared a star-shaped thiophene derivative P6 consisting of one central core of phenyl and three arms of bithiophene by electrochemical polymerization (Fig. 5d).…”
Section: Ec Materials For Color Camouflagementioning
Electrochromic (EC) materials and devices, whose optical properties (color, reflectance, emittance, etc.) can be manipulated by switching a low-voltage bias, show great promise in many applications such as smart windows,...
“…3(f ) and 4(c)). [46][47][48] The switching response time and stability of the polymer films are evaluated using successive square-wave potentials, and the results are shown in Fig. 4.…”
Color-to-white switching electrochromic devices (ECDs) present great application potential in non-emissive displays and energy-saving fields, but there are still very few reports.
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