The effective separation and efficient transportation
of photogenerated
carriers within a photoanode are critical factors for achieving outstanding
photoelectrochemical (PEC) water splitting. In this study, TiO2-ferrihydrite (Fh)-MXene nanowire arrays (NWAs) are fabricated
by a hydrothermal method followed by spin coating. TiO2-Fh-MXene NWAs achieved a photocurrent density of 1.44 mA/cm2 at 1.23 V versus the reversible hydrogen electrode (vs RHE),
surpassing TiO2-Fh by 2.05 times and TiO2 by
2.93 times. According to the electrochemical impedance spectroscopy,
photoluminescence, and Mott–Schottky measurements, the significant
enhancement in the separation of photogenerated electron–hole
pairs and efficient carrier transportation are ascribed to the integration
of Fh and MXene, respectively. Additionally, the light absorption
of TiO2 NWAs is improved with the incorporation of the
Fh-MXene layer. This work provides valuable insights into the fabrication
of photoanodes, especially using wide bandgap materials.