Bismuth(III) thioether chemistry: synthesis and structure of a coordination polymer derived from BiCl3 and MeSi(CH2SMe)3

Yim, Hing W.; Lam, Kwok L.; Rheingold, Arnold L.; Rabinovich, Daniel

doi:10.1016/s0277-5387(00)00328-4

Cited by 17 publications

(7 citation statements)

References 28 publications

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“…There are therefore two different distorted octahedral Bi environments, one with bidentate coordination to one tripod and four Cl's, and the other with bidentate coordination to one tripod and monodentate coordination to another, and three Cl's. 41 The [BiCl 3 ([12] replaced by up to six secondary Bi ؒ ؒ ؒ S interactions. 42, 43 The related [(BiCl 3 ) 2 ([24]aneS 8 )] involves two eight-coordinate Bi() centres with five macrocyclic S atoms (two of which bridge the Bi centres) and three Cl's.…”

Section: Group 15mentioning

confidence: 99%

Macrocyclic and polydentate thio- and seleno-ether ligand complexes of the p-block elements

Levason

Reid

2001

J. Chem. Soc., Dalton Trans.

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The diverse structures exhibited by complexes of p-block (Group 13-15) halides with acyclic and macrocyclic thio-, seleno-, and telluro-ethers are described. Examples range from six-coordinate monomers through to one-, twoor three-dimensional network infinite polymers with structural motifs often very different to those found with d-block elements. BondingAlthough it has received much less theoretical effort than in transition metal analogues, bonding in main group complexes where the octet rule is formally exceeded, has attracted considerable recent interest. The original model invoking nd orbital involvement leading to for example, central atom sp 3 d 2 bonding Bill Levason obtained his BSc and PhD from UMIST and was appointed to a lectureship in Southampton in 1976, promoted to senior lecturer 1988, reader 1994 and Professor of Inorganic Chemistry in 1999 His research interests include the synthesis and coordination chemistry of selenium, tellurium, antimony and bismuth donor ligands, early transition metal chemistry, main group coordination chemistry, and heteropolyanions. He has co-authored over 300 research papers. Bill LevasonGill Reid gained her BSc and PhD from the University of Edinburgh. Following a postdoctoral fellowship, she took up a lectureship in Inorganic Chemistry at the University of Southampton in 1991 and was promoted to senior lecturer in 1999. Her research interests are wide-ranging, encompassing many aspects of macrocyclic, transition metal and main group coordination chemistry, including the synthesis of macrocyclic and polydentate ligands involving Group 15 (P and As) and Group 16 (S, Se and Te) donor atoms, studies of their coordinating properties with metal ions and organometallic fragments and the synthesis and properties of metallocyclic species. She has co-authored over 120 research papers on aspects of this work.

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Section: Group 15mentioning

confidence: 99%

Macrocyclic and polydentate thio- and seleno-ether ligand complexes of the p-block elements

Levason

Reid

2001

J. Chem. Soc., Dalton Trans.

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“…Although their coordination chemistry is yet to be fully exploited, a number of transition and main group metal complexes thereof have been synthesized in recent years, including group 6 metal tricarbonyl derivatives (Tts R )M(CO) 3 (M ¼ Cr, Mo, W) [1,2] and polynuclear compounds of copper(I) [3,4] and bismuth(III) [5]. The syntheses of the tetradentate thioethers Si(CH 2 SR) 4 (R ¼ Me, Ph) and their mercury(II) derivatives {Si(CH 2 SR) 4 }HgBr 2 , both of which exhibit one-dimensional polymeric structures in the solid state, have also been reported [6].…”

Section: Introductionmentioning

confidence: 99%

Bis(thioether)silanes: Synthesis and characterization of tin(IV) complexes with new dithioether ligands

Lozano-Lewis¹,

John-Rajkumar²,

Islas³

et al. 2007

Main Group Chemistry

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The bis(thioether)silanes Me 2 Si(CH 2 SR) 2 (abbreviated Bts R , where R ¼ Me or Pr i ), the first two members of a new family of bidentate thioether ligands, have been readily prepared and fully characterized. The tin(IV) tetrahalide derivatives (Bts R )SnX 4 (X ¼ Cl, Br), which comprise the first four metal coordination complexes of these new sulfur-donor ligands, have also been isolated, and the X-ray structure of the tetrabromide derivative (Bts Me )SnBr 4 confirms the chelating nature of the dithioether.

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“…The product is a 1:1 polymer containing single 2 -Cl bridged Cl 2 Bi Cl BiCl 3 units. There are therefore two different distorted octahedral Bi environments, one with bidentate coordination to one tripod and four Cl's, and the other with bidentate coordination to one tripod and monodentate coordination another, and three Cl's [36].…”

Section: Selenoether Ligandsmentioning

confidence: 99%

Recent developments in thio‐, seleno‐, and telluro‐ether ligand chemistry

Barton

Genge

Hill

et al. 2002

Heteroatom Chemistry

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Bismuth(III) thioether chemistry: synthesis and structure of a coordination polymer derived from BiCl3 and MeSi(CH2SMe)3

Cited by 17 publications

References 28 publications

Macrocyclic and polydentate thio- and seleno-ether ligand complexes of the p-block elements

Macrocyclic and polydentate thio- and seleno-ether ligand complexes of the p-block elements

Bis(thioether)silanes: Synthesis and characterization of tin(IV) complexes with new dithioether ligands

Recent developments in thio‐, seleno‐, and telluro‐ether ligand chemistry

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