2010
DOI: 10.1107/s1600536810005945
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Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdo(V,VI)phosphate hexahydrate

Abstract: Key indicators: single-crystal X-ray study; T = 293 K; mean (C-C) = 0.042 Å; Hatom completeness 78%; disorder in main residue; R factor = 0.053; wR factor = 0.155; data-to-parameter ratio = 12.2. 2+ cation is in a distorted octahedral environment, coordinated by six N atoms from three chelating 3-(2-pyridyl)-1H-pyrazole ligands. In the one-electron reduced heteropolyanion, two O atoms of the central PO 4 group (1 symmetry) are equally disordered about an inversion centre. N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bon… Show more

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Cited by 2 publications
(2 citation statements)
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“…Similarly, bidentate iron chelation by the pyrazolylpyrimidinones from the pyrimidinone nitrogen and pyrazole nitrogen as depicted in Figure b may be hypothesized. A single-crystal X-ray structure of the pyrazolylpyridines–Fe complex is reported in the literature which supports this hypothesis. , This aspect of metal chelation by the compounds was considered while planning further SAR exploration and target identification studies with the series.…”
Section: Results and Discussionmentioning
confidence: 62%
See 1 more Smart Citation
“…Similarly, bidentate iron chelation by the pyrazolylpyrimidinones from the pyrimidinone nitrogen and pyrazole nitrogen as depicted in Figure b may be hypothesized. A single-crystal X-ray structure of the pyrazolylpyridines–Fe complex is reported in the literature which supports this hypothesis. , This aspect of metal chelation by the compounds was considered while planning further SAR exploration and target identification studies with the series.…”
Section: Results and Discussionmentioning
confidence: 62%
“…A single-crystal X-ray structure of the pyrazolylpyridines–Fe complex is reported in the literature which supports this hypothesis. 8 , 9 This aspect of metal chelation by the compounds was considered while planning further SAR exploration and target identification studies with the series.…”
Section: Results and Discussionmentioning
confidence: 99%