Bis (trichlorophosphine)iminium hexachlorophosphate

Formation and Crystal Structure of 2,3,5-Triphenyltetrazolium Hexachlorophosphate and Dichlorophosphate(V), [TPT]+[PCl6]– and [TPT]+[PO2Cl2]–

“…[2], and they are only given in footnote 1 below Table 4. A vibrational analysis for the octahedral [PCl 6 ] − unit delivers [31]: Table 4). The vibrational frequencies of [PCl 6 ] − are all consistent with the octahedral structure and in agreement with other experimental values [10,12,32]. The strongest Raman band at 354 cm −1 belongs to ν 1 / A 1g , the medium Raman mode at 262 cm −1 to ν 2 / E g and the one at 240 cm −1 to ν 5 / F 2g .…”

Chemistry of Boratophosphazenes: Synthesis of Borazine-Phosphazene Hybrid Cations, and New Inorganic Heterocycles by Skeletal Substitution Reactions

“…This can be explained by the strong bonding between boron and oxygen, and suggests that the triflate anion is more coordinating than the Group 13 tetrahalide anions. 19 F NMR spectroscopy in CDCl 3 , which showed a singlet resonance at d À 77.4 that is similar to that observed for triflic acid (d À 78.48), [31] and the 13 C NMR spectrum showed a quartet resonance at d 118.3 assigned to the CF 3 group in addition to the methyl resonance at d 31.2.…”

“…Thus the As and Sb atoms were found to replace boron in a skeletal substitution reaction forming novel arsenic (v) . In solution, a complex fluxional behavior was observed for 9 by variable-temperature 19 F and 31 P NMR spectroscopy. With the discovery of the skeletal substitution reactions, questions were raised with regard to the mechanism of formation of 8 from the reaction of Ag [BF 4 ] and 1.…”

“…At room temperature, the 19 F NMR spectrum of a pure sample of 9 in CDCl 3 or CD 2 exhibit fluxional behavior in solution. [35] Consideration of the boat structure (9 boat ) determined by X-ray crystallography suggests that three types of chemically different fluorine environments should be observed (two types of F ax (F ' ax and F '' ax ) and one type of F eq ).…”

“…bonds in [Cl 3 PNPCl 3 ] are 1.51 ± 1.56 long, [19] and a typical P ± N single bond is 1.78 . [20] Significantly, however, the P(1) ± N(1) and P(2) ± N(2) bonds (av 1.593(5) ) are similar in length to the P ± N bonds in (NPCl 2 ) 3 (1.58 ), [21] which suggests that the lone pairs on N(1) and N(2) are involved in the p bonding to the phosphorus atoms of the P(1)-N(3)-P(2) fragment.…”