Bis(fluoroalkyl)acrylic and methacrylic phosphate monomers, their polymers and some of their properties

Timperley, Christopher M.; Arbon, Robert; Bird, Michael R.; Brewer, Stuart A.; Parry, Malcolm W.; Sellers, David J.; Willis, Caroline

doi:10.1016/s0022-1139(02)00314-7

Cited by 33 publications

(19 citation statements)

References 38 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…52 Perfluoroalkyl phosphate acrylates monomers have also been reported. 53,54 However, the C n F 2n+1 (n > 7) chains are too stable, bioaccumulable, toxic, and persistent. 55 In particular, perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) have been serious concerns since the 1990s, and a list of chemicals that can degrade to fluorinated carboxylic acids is reported in ref 56.…”

Section: Synthesis Of Fluorinated Monomersmentioning

confidence: 99%

Fluorinated Oligomers and Polymers in Photopolymerization

2015

View full text Add to dashboard Cite

Section: Synthesis Of Fluorinated Monomersmentioning

confidence: 99%

Fluorinated Oligomers and Polymers in Photopolymerization

2015

View full text Add to dashboard Cite

“…Polyacrylate latex modified by organic fluorine, often referred as fluorinated polyacrylate latex, shows many unique properties, such as excellent inertness to solvents, acids, alkalis, and moisture adsorption as well as interesting oil and water repellency, due to the low surface energy and easy migration of organic fluorine [35][36][37][38][39][40][41].…”

Section: Polyacrylate Latex Modified By Organic Fluorinementioning

confidence: 99%

Recent advances in the modification of polyacrylate latexes

Bao

Zhang

et al. 2015

J Mater Sci

View full text Add to dashboard Cite

Polyacrylate latexes present good film-forming property, and therefore are used in a wide range of applications including coatings, adhesives, additives for paper, textiles, wood, and leather. However, some drawbacks, such as poor elasticity and low hardness have restricted their applications. This review summarizes recent development of polyacrylate latexes modified by polyurethane, organic fluorine, and inorganic nanoparticles, separately, which most often exhibit superior properties to those of their individual components. For each modification method, a comment is given based on our knowledge and related research experience. At last, some perspectives on the future research and development of modification of polyacrylate latexes are concluded.

show abstract

“…Fluorinated acrylate emulsions have attracted increasing research attention because the various films fabricated from these nanoparticles not only maintain their original properties, such as good matrix adhesion [1], but also exhibit unique properties, such as high thermal and chemical resistance [2][3][4], water repellency, good oxidation resistance, and strong fluorine electronegativity. However, they are limited in some applications; for example, the fluorinated films exhibit a poor anti-fouling property in seawater because when perfluoroalkyl-containing polymers contact with water, the perfluoroalkyl groups on the surface migrate toward the polymer, reducing their interfacial free energy, while the non-fluorinated groups migrate toward the interface.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of Poly (Methyl Methacrylate-Co-Butyl Acrylate)/Perfluorosilyl Methacrylate Core–Shell Nanoparticles: Novel Approach for Optimization of Coating Process

Kook

Kim

et al. 2018

Preprint

View full text Add to dashboard Cite

In this study, the coating order of two monomers in the shell polymerization process of coreshell nanoparticles was altered to facilitate easy coating and optimize the properties of the coated surface to simplify the additional coating formulation process. To obtain a glass transition temperature suitable for coating, a core was synthesized by the copolymerization of an acryl monomer. A perfluoro monomer and silane monomer were additionally added to synthesize nanoparticles exhibiting both water-oil repellency and anchoring properties. In order to realize various surface properties, the nanoparticles underwent surface modification and cellulose fiber was introduced. Through the various data described in this text, the surface properties improved with the order of introduction of the two monomers.

show abstract

Bis(fluoroalkyl)acrylic and methacrylic phosphate monomers, their polymers and some of their properties

Cited by 33 publications

References 38 publications

Fluorinated Oligomers and Polymers in Photopolymerization

Fluorinated Oligomers and Polymers in Photopolymerization

Recent advances in the modification of polyacrylate latexes

Synthesis of Poly (Methyl Methacrylate-Co-Butyl Acrylate)/Perfluorosilyl Methacrylate Core–Shell Nanoparticles: Novel Approach for Optimization of Coating Process

Contact Info

Product

Resources

About