Bis axially coordinated (phthalocyaninato)ruthenium(II) compounds

Kobel, Wolfram; Hanack, Michael

doi:10.1021/ic00221a027

Cited by 181 publications

(75 citation statements)

References 2 publications

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“…In recent years, there has been an active and concerted attention in developing metal-organic coordination materials owing to their potentially useful magnetic, electric, photochemical and catalytic properties (Kubo, 1976;Kobel & Hanack, 1986;Pierpont & Jung, 1994;Huskins & Robson, 1990 is presented, which has been obtained in continuation of our studies of new coordination compounds (Kaabi, et al, 2010).…”

Section: S1 Commentmentioning

confidence: 85%

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Diaquabis(perchlorato)(1,10-phenanthroline)copper(II)

Kaabi¹,

Glaoui²,

Zeller³

et al. 2010

Acta Cryst E

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Key indicators: single-crystal X-ray study; T = 100 K; mean (C-C) = 0.002 Å; R factor = 0.024; wR factor = 0.074; data-to-parameter ratio = 19.0.In the title compound, [Cu(ClO 4 ) 2 (C 12 H 8 N 2 )(H 2 O) 2 ], the Cu II atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water molecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms of two weakly bonded perchlorate anions, thus yielding a strongly distorted CuN 2 O 4 octahedral environment. The crystal packing is stabilized by O-HÁ Á ÁO hydrogen bonds between the water molecules and the perchlorate anions. In addition, the organic molecules are associated by -stacking interactions between symmetry-equivalent antiparallel non-nitrogen aromatic rings, with interplanar distances of 3.543 (2) Å . Related literature

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Section: S1 Commentmentioning

confidence: 85%

“…For common applications of metal-organic coordination compounds, see: Kubo (1976); Kobel & Hanack (1986); Pierpont & Jung (1994); Huskins & Robson (1990). For a related structure, see: Kaabi et al (2010).…”

Section: Related Literaturementioning

confidence: 99%

Diaquabis(perchlorato)(1,10-phenanthroline)copper(II)

Kaabi¹,

Glaoui²,

Zeller³

et al. 2010

Acta Cryst E

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“…Some years ago we reported the synthesis of pure phthalocyaninatoruthenium(II) (PcRu) by thermal decomposition of PcRu(DMSO) 2 Á2DMSO [1]. Later we developed a more convenient method for the preparation of pure PcRu via the corresponding bisisoquinoline complex PcRu(iqnl) 2 [2] which is readily available and can be thermally decomposed at 250°C with formation of pure PcRu [3].…”

Section: Introductionmentioning

confidence: 99%

“…The disubstituted complex 4, which could only be isolated in a very small amount, was simply characterized as a mixture of isomers by its 1 H NMR spectrum (in Scheme 1, formula 4 shows only one of the five possible isomers which were not separated).…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Properties of Tetrakis(trimethylsilyl)-phthalocyaninatoruthenium(II)

Dürr

Hanack

1999

J. Porphyrins Phthalocyanines

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Tetrakis(trimethysilyl)phthalocyaninatoruthenium(II) (5) has been synthesized via the biaxially coordinated (( CH 3)3 Si )4 PcRu (3- Clpy )2 (2) complex by thermal decomposition of the axial ligands of 2. (( CH 3)3 Si )4 PcRu (5) was characterized by NMR, IR and UV-vis spectroscopy and elemental analysis. The trisubstituted (( CH 3)3 Si )3 PcRu (3- Clpy )2 (3) and disubstituted (( CH 3)3 Si )2 PcRu (3- Clpy )2 (4) complexes, formed as side products during the thermolysis of 2, could be isolated and characterized.

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“…The aza-nitrogen and peripheral fused benzene ring imparts chemical and thermal stability to the phthalocyanine macromolecule. The optical properties of metal phthalocyanine complexes have been studied extensively for several decades [1][2][3]. The low solubility of these complexes combined with the intense π−π* bands associated with phthalocyanine ligand led to the industrial applications as pigments in paints and dyestuffs [4].…”

Section: Introductionmentioning

confidence: 99%