Bis(4-benzylpiperidine-1-carbodithioato-κ2S,S′)dimethyltin(IV)

Rehman, Zia ur; Ali, Saqib; Muhammed, Niaz; Meetsma, Auke

doi:10.1107/s1600536806056236

Cited by 5 publications

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“…Thus, the coordination geometry about Sn in 6 is best described as distorted skew trapezoidal-bipyramidal. The geometry and bond lengths of the SnC 2 S 4 core are comparable with those usually observed for related octahedral complexes [23]. The packing diagram ( figure 4) shows that the supramolecular structure of 6 mediated by secondary -H and CH 3 O-H interactions.…”

Section: X-ray Structuressupporting

confidence: 58%

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Supramolecular organotin(IV) dithiocarboxylates as potential antimicrobial agents

Rehman

Muhammady

Shah

et al. 2012

Journal of Coordination Chemistry

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A series of tri-, chlorodi-, and diorganotin(IV) derivatives of 4-(2-methoxyphenyl)piperazine-1-carbodithioate (L) {R ¼ n-C 4 H 9 (1), C 6 H 11 (2), CH 3 (3) and C 6 H 5 (4)}, (n-C 4 H 9 ) 2 SnClL (5) and R 2 SnL 2 {R ¼ n-C 4 H 9 (6), C 2 H 5 (7), CH 3 (8)} have been synthesized by refluxing organotin(IV) chlorides with the ligand-salt in the appropriate molar ratio. Elemental analysis, Raman, IR, multinuclear NMR ( 1 H, 13 C and 119 Sn), mass spectroscopic, and single-crystal X-ray crystallographic studies were undertaken to elucidate the structures of the new compounds both in solution and in the solid state. The X-ray diffraction work reveals supramolecular structures for 4 and 6, with distorted trigonal-bipyramidal and distorted octahedral geometries around Sn, respectively. The ligand and several of the new compounds are good antimicrobial agents.

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Section: X-ray Structuressupporting

confidence: 58%

“…161-163 C. Anal. Calcd (Found, %), for C 23 2.2.1b. General procedure for the synthesis of complexes.…”

Section: Synthesismentioning

confidence: 99%