Abstract:On the basis of the data about the peculiarities of dielectric and opticał properties in the vicinity of 7'2 one can made the conclusion about the ferroelectric character of the phase, situated between T*2 and Tcool2.
“…Only for the low temperature phase of [N(C 2 H 5 ) 4 ] 2 ZnCl 4 (below T 1 ) the X‐ray diffraction data revealed mmm point symmetry which correlates with the corresponding domain structure . Meanwhile, on the basis of domain structure observation the monoclinic structure was suggested below T 2 in [N(C 2 H 5 ) 4 ] 2 ZnBr 4 .…”
Thermodynamically induced structural transformation to a polar phase in the tetraethylammonium tetrahalogenocobaltate solid solution of [N(C 2 H 5 ) 4 ] 2 CoClBr 3 (TEACCB-3) is found to be accompanied with a large dielectric permittivity peak near 258 K. It was also found that the sample undergoes a ferrimagnetic ordering on further cooling below 8 K. Our results demonstrate that crystalline ferroics with an alkylammonium cation can develop strong magnetic interactions reaching 2.3 m B fu À1 at 14 T that can potentially coexist with electric polarization at the same temperature region.
“…Only for the low temperature phase of [N(C 2 H 5 ) 4 ] 2 ZnCl 4 (below T 1 ) the X‐ray diffraction data revealed mmm point symmetry which correlates with the corresponding domain structure . Meanwhile, on the basis of domain structure observation the monoclinic structure was suggested below T 2 in [N(C 2 H 5 ) 4 ] 2 ZnBr 4 .…”
Thermodynamically induced structural transformation to a polar phase in the tetraethylammonium tetrahalogenocobaltate solid solution of [N(C 2 H 5 ) 4 ] 2 CoClBr 3 (TEACCB-3) is found to be accompanied with a large dielectric permittivity peak near 258 K. It was also found that the sample undergoes a ferrimagnetic ordering on further cooling below 8 K. Our results demonstrate that crystalline ferroics with an alkylammonium cation can develop strong magnetic interactions reaching 2.3 m B fu À1 at 14 T that can potentially coexist with electric polarization at the same temperature region.
In this paper dielectric permittivity and birefringence of [N(C2H5)4]2MeCl2Br2 (Me = Zn, Co, Cu) have been investigated. As the results of our measurements we present structural phase transitions in these ferroelectric crystals.
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