Birefringence, Photo luminous, Optical Limiting and Third Order Nonlinear Optical Properties of Glycinium Phosphite (GlP) Single Crystal: A potential Semi Organic Crystal for Laser and Photonics Applications

Krishnan, Rajesh; Ayyanar, Mani; Kasinathan, Anandan; Kumar, P. Praveen

doi:10.1590/1980-5373-mr-2017-0329

Cited by 7 publications

(3 citation statements)

References 22 publications

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“…small molecule organic materials without an inversion centre (Horiuchi & Tokura, 2008). Among these materials, glycinium phosphite, NH 3 CH 2 COOHÁ-H 2 PO 3 (GPI), is one of the most extensively studied crystalline compounds as a result of its ferroelectric, piezoelectric and also nonlinear optical properties (Tchukvinskyi et al, 1998;Wiesner, 2003;Krishnan et al, 2018). At room temperature, the material crystallizes in the centrosymmetric monoclinic space group P2 1 /a (Averbuch-Pouchot, 1993;Shikanai et al, 2003) and stays paraelectric down to 225 K. Cooling below 224-225 K results in a phase transition into a low-temperature ferroelectric phase (Dacko et al, 1996;Tchukvinskyi et al, 1998).…”

Section: Introductionmentioning

confidence: 99%

Phase transition in an organic ferroelectric: glycinium phosphite, with and without X-ray radiation damage

Bogdanov

Zakharov

Chernyshov

et al. 2021

Acta Crystallogr B Struct Sci Cryst Eng Mater

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Thermal evolution of an organic ferroelectric, namely, glycinium phosphite, was probed by multi-temperature single-crystal diffraction using synchrotron radiation and also by a similar experiment with a laboratory X-ray diffractometer. Both series of measurements showed a transition from the paraelectric to the ferroelectric state at nearly the same temperature, T c = 225 K. Temperature evolution of the unit-cell parameters and volume are drastically different for the synchrotron and laboratory data. The latter case corresponds to previous reports and shows an expected contraction of the cell on cooling. The data collected with the synchrotron beam show an abnormal nonlinear increase in volume on cooling. Structure analysis shows that this volume increase is accompanied by a suppression of scattering at high angles and an apparent increase of the anisotropic displacement parameters for all atoms; we therefore link these effects to radiation damage accumulated during consecutive data collections. The effects of radiation on the formation of the polar structure of ferroelectric glycinium phosphite is discussed together with the advantages and drawbacks of synchrotron experimentation with fine temperature sampling.

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Section: Introductionmentioning

confidence: 99%

Phase transition in an organic ferroelectric: glycinium phosphite, with and without X-ray radiation damage

Bogdanov

Zakharov

Chernyshov

et al. 2021

Acta Crystallogr B Struct Sci Cryst Eng Mater

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“…A good pattern indicates good quality single crystal. [ 38 ] The phenomenon called interference technique is developed between the two components when laser is passed through the sample, such as extraordinary ray and ordinary ray. The fringes of these two rays are at equal line spacing, and their shapes show qualitatively better refractive index homogeneity.…”

Section: Resultsmentioning

confidence: 99%

Study of the Crystalline Perfection, Homogeneity, Chemical Etching on the Surface, and Third‐Order Nonlinear Optical Properties of (1 1 0) Oriented Hydroxyethylammonium D‐Tartrate Monohydrate Single Crystal and Hirshfeld Surface Analysis

Hakkim¹,

Rajesh²,

Sidden³

et al. 2022

Cryst. Res. Technol.

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The single crystal of hydroxyethylammonium D-tartrate monohydrate (HEDT) is grown along the (1 1 0) plane using the Sankaranarayanan-Ramasamy method. The powder X-ray diffraction and the high-resolution X-ray diffraction analyses are used to corroborate the growth plane and perfection of the crystallinity, respectively. The birefringence experiment has proven crystalline homogeneity and estimated birefringence value (𝚫n) is 0.109. The surface morphology of the grown crystal is examined by chemical etching analysis and irregular hillock patterns are found. The transmittance for the (1 1 0) plane of the HEDT is inspected by a UV-Vis analysis. The second harmonic generation efficiency of the HEDT crystal is 1.7 times that of potassium dihydrogen phosphate (KDP). The third-order nonlinear optical (TONLO) properties of the grown HEDT crystal are scrutinized by the Z-scan experiment. The estimated TONLO susceptibility of HEDT crystal is 6.827 × 10 −8 esu. The laser damage threshold value of HEDT is discovered to be 5.24 GW cm −2 . The 3D Hirshfeld surface visualizes the interaction between HEDT molecules and analyzes the distance from the surface of the molecule to the farthest and the nearest atom. The important contributions of crystal packing are explored by 2D-fingerprint plots.

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“…Glycinium phosphite, NH 3 CH 2 COOHÁH 2 PO 3 (GPI), is one of the promising candidates to face the challenges in the field of new technologies based on electrical polarization properties. It is one of the most extensively studied compounds, due to its ferroelectric, piezoelectric and also non-linear optical properties (Tchukvinskyi et al, 1998;Wiesner, 2003;Krishnan et al, 2018). At room temperature, GPI crystallizes in the centrosymmetric monoclinic space group P2 1 /a (Averbuch-Pouchot, 1993;Shikanai et al, 2003) and stays paraelectric down to 225 K. Cooling below 225-224 K results in a phase transition into a low-temperature ferroelectric phase (Dacko et al, 1996;Tchukvinskyi et al, 1998).…”

Section: Introductionmentioning

confidence: 99%

The effect of hydrostatic compression on the crystal structure of glycinium phosphite

Bogdanov¹,

Korabelnikov²,

Fedorov³

et al. 2022

Acta Crystallogr Sect B

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The crystal structure of glycinium phosphite (GPI) was studied in the pressure range from ambient to 6.5 GPa at 293 K using single-crystal X-ray diffraction. The changes in the unit-cell volume and parameters were continuous and anisotropic. The major compression was observed normal to the direction of the spontaneous polarization that occurs in this structure during a ferroelectric phase transition on cooling, whereas the structural compression along the b axis coinciding with the 21 axis was almost zero. The effect of pressure on the hydrogen bonds linking the H2PO3 tetrahedra into zigzag chains along the c axis was different from that on the hydrogen bonds connecting the glycinium cations with the H2PO3 tetrahedra in the (b × c) plane. The discontinuous changes in the geometries of selected hydrogen bonds at about 1.21 GPa may be evidence of a phase transition, e.g. into an ordered ferroelectric phase (with ordered positions of protons). The anisotropy of compression of GPI in the ferroelectric state (at 0 K) was studied using DFT calculations taking into account dispersive van der Waals interactions. The calculations predicted negative linear compressibility along the b axis.

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Birefringence, Photo luminous, Optical Limiting and Third Order Nonlinear Optical Properties of Glycinium Phosphite (GlP) Single Crystal: A potential Semi Organic Crystal for Laser and Photonics Applications

Cited by 7 publications

References 22 publications

Phase transition in an organic ferroelectric: glycinium phosphite, with and without X-ray radiation damage

Phase transition in an organic ferroelectric: glycinium phosphite, with and without X-ray radiation damage

Study of the Crystalline Perfection, Homogeneity, Chemical Etching on the Surface, and Third‐Order Nonlinear Optical Properties of (1 1 0) Oriented Hydroxyethylammonium D‐Tartrate Monohydrate Single Crystal and Hirshfeld Surface Analysis

The effect of hydrostatic compression on the crystal structure of glycinium phosphite

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