Biphenyl-4-carbaldehyde azine

In the title compound, C30H36N2O2S, the dihedral angle between the two aromatic rings of the biphenyl residue is 31.2 (1)°. The two methylene C atoms subtend an angle of 99.9 (1)° at the S atom. In the crystal, molecules form inversion dimers linked by pairs of N—H⋯O hydrogen bonds. The hydroxyl group is shielded by the tert-butyl residues and is therefore not involved in any hydrogen bonding.

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N′-[(Biphenyl-4-yl)methylene]-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetohydrazide

Yehye

Ariffin

Rahman

et al. 2010

Acta Cryst E

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Biphenyl-4-carbaldehyde azine

Abstract: The complete molecule of the title compound, C26H20N2, is generated by crystallographic inversion symmetry. The terminal phenyl ring is twisted by 19.2 (1)° with respect to the adjacent phenylene ring.

Cited by 1 publication

References 7 publications

N′-[(Biphenyl-4-yl)methylene]-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetohydrazide

N′-[(Biphenyl-4-yl)methylene]-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetohydrazide

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Biphenyl-4-carbaldehyde azine

Abstract: The complete mol­ecule of the title compound, C26H20N2, is generated by crystallographic inversion symmetry. The terminal phenyl ring is twisted by 19.2 (1)° with respect to the adjacent phenyl­ene ring.

Cited by 1 publication

References 7 publications

N′-[(Biphenyl-4-yl)methylene]-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetohydrazide

N′-[(Biphenyl-4-yl)methylene]-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetohydrazide

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Product

Resources

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Abstract: The complete molecule of the title compound, C26H20N2, is generated by crystallographic inversion symmetry. The terminal phenyl ring is twisted by 19.2 (1)° with respect to the adjacent phenylene ring.