Abstract:The main biodegradation product of (AE)--isomethylionone (2) with standard activated sludge was characterized as (AE)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)propan-2-one (1) by its analysis and synthesis. Both enantiomers (1a and 1b) of 1 were synthesized by starting from (R)-and (S)-2,4,4-trimethyl-2-cyclohexen-1-ol (3a and 3b), respectively.
Enantioselective synthesis and absolute stereochemistry of both the enantiomers of transmagnolione, a fragrance structurally related to trans-methyl jasmonate.
Enantioselective synthesis and absolute stereochemistry of both the enantiomers of transmagnolione, a fragrance structurally related to trans-methyl jasmonate.
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