Angewandte Chemie
 1999
DOI: 10.1002/(sici)1521-3757(19990201)111:3<413::aid-ange413>3.3.co;2-x
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Biosynthese des Psoralens: zum Mechanismus einer Cytochrom-P450-katalysierten, oxidativen Bindungsspaltung

Volker Stanjek
1
,
Martin Miksch
2
,
Patricia Lueer3
et al.

Abstract: Nicht schrittweise wie bei der oxidativen Dealkylierung von Steroiden [Gl. (1)], sondern in nur einem Schritt wird (+)‐Marmesin 1 durch die Psoralen‐Synthase (ein Cytochrom P450) im Sinne einer syn‐Eliminierung zum phototoxischen Psoralen 2 und Aceton dealkyliert.

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