Biomimetic Total Synthesis of Scabellone B

Tao, Yu; Shu, Xin; Yang, Ke‐Wu; Hu, Xiangdong

doi:10.1055/s-0037-1610178

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Biomimetic Dimerization In the Synthesis Of Scabellone B1

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2020

2023

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“…Commercially available 46 was the starting material of our synthesis (Scheme 7 ). 20 The sequenced introduction of TMS and geranyl groups gave compound 47 in 78% overall yield. With the removal of the TMS group, the key precursor 41 was obtained readily.…”

Section: Biomimetic Dimerization In the Synthesis Of Scabellone Bmentioning

confidence: 99%

Investigations on Biomimetic Dimerization in Natural Product Synthesis

Zhang¹,

Chen²,

Hu³

2023

Synlett

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Biomimetic dimerization is a fascinating pathway to natural product synthesis. By using structurally inferior monomers, complex molecular architectures can be readily established with distinct efficiency and elegance. In this Account, our investigation on biomimetic dimerization in natural product synthesis has been summarized, which includes our synthetic exploration of linderaspirone A, bi-linderone, parvistemin A, (±)-diperezone, scabellone B, and spiroxins A/C/D.

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Section: Biomimetic Dimerization In the Synthesis Of Scabellone Bmentioning

confidence: 99%

Investigations on Biomimetic Dimerization in Natural Product Synthesis

Zhang¹,

Chen²,

Hu³

2023

Synlett

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Six-Membered Ring Systems: With O and/or S Atoms

Santos¹,

Silva²

2020

Progress in Heterocyclic Chemistry

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This book and the individual contributions contained in it are protected under copyright by the Publisher (other than as may be noted herein). NoticesKnowledge and best practice in this field are constantly changing. As new research and experience broaden our understanding, changes in research methods, professional practices, or medical treatment may become necessary.Practitioners and researchers must always rely on their own experience and knowledge in evaluating and using any information, methods, compounds, or experiments described herein. In using such information or methods they should be mindful of their own safety and the safety of others, including parties for whom they have a professional responsibility.

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Biomimetic Total Synthesis of Scabellone B

Cited by 2 publications

References 3 publications

Investigations on Biomimetic Dimerization in Natural Product Synthesis

Investigations on Biomimetic Dimerization in Natural Product Synthesis

Six-Membered Ring Systems: With O and/or S Atoms

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