Significance and Impact of the Study: Microbial accumulation and volatilization are natural processes involved in biogeochemical cycles of elements. Despite their impact on mobility, bioavailability and toxicity of various metal(loid)s, only few papers deal with these processes under aerobic conditions with microscopic fungi. Thus, the proving of ability of microscopic fungus Scopulariopsis brevicaulis to accumulate and transform metals and metalloids by methylation or alkylation and quantification of these processes were demonstrated. The results can provide basic information on natural elements cycling and background for more specific studies focusing, for example, on application of these processes in mitigation of metal(loid) contamination. Abstract Biovolatilization and bioaccumulation capabilities of different elements by microscopic filamentous fungus Scopulariopsis brevicaulis were observed. Accumulation of As(III), As