Abstract:Climate change, environmental impact and the limited natural resources urge scientific research and novel technical solutions. The monograph series Green Energy and Technology serves as a publishing platform for scientific and technological approaches to "green"-i.e. environmentally friendly and sustainable-technologies. While a focus lies on energy and power supply, it also covers "green" solutions in industrial engineering and engineering design. Green Energy and Technology addresses researchers, advanced st… Show more
“…Interest in alternative fuel solutions has increased over the years, and the transportation industry and governments are making a concerted effort to move to renewable and eco-friendly solutions to meet ever more stringent emissions and pollution standards (Patterson et al, 2011;Mustafi et al, 2020;Koonaphapdeelert et al, 2020;Korberg et al, 2020;Rafiee et al, 2021). Despite electric vehicles being heralded as the future of the industry, the use of the internal combustion engine is expected to play a dominant role for the upcoming decades due to existing investment in such technologies along with its widespread use.…”
The localised forced ignition and subsequent flame propagation have been analysed for stoichiometric biogas-air mixtures (CH 4 /CO 2 /air blend) with different spatial distributions (uniform, Gaussian and bimodal) and mean levels of CO 2 dilution (i.e. mole fraction of CO 2 ) for different flow conditions (e.g. quiescent laminar condition and different turbulence intensities) using three-dimensional Direct Numerical Simulations. A two-step chemical mechanism with sufficient accuracy is used to capture the effects of CO 2 dilution on the laminar burning velocity of the biogas − air mixture. A parametric analysis in terms of the mean, standard deviation and integral length scale of the initial Gaussian and bimodal distributions of spatial CO 2 dilution in the unburned gas has been conducted. Qualitatively similar behaviour has been observed for all three initial spatial distributions of CO 2 . A departure from uniform conditions was found to increase the range of reaction rate magnitudes of CH 4 , which impacts the burned gas volume and, in turn, increases the variability of the outcomes of the ignition event (successful thermal runaway and subsequent self-sustained propagation or misfire). Turbulence intensity and the mean level of dilution were found to have significant impacts on the outcome of the localised forced ignition, and an increase of either quantity acts to reduce the burned gas volume irrespective of mixture composition due to the enhancement of heat transfer from the hot gas kernel, and the heat sink effects of CO 2 , respectively. An increase of the integral length scale 𝑙 𝜓 for the spatial distribution of CO 2 dilution increased the probability of a successful outcome of the ignition event. A uniform initial spatial distribution was found to be optimal, and in the case of a departure from nonuniform conditions, larger variability in the outcome are obtained for a Gaussian initial distribution of CO 2 dilution than a bimodal one. The variance of the CO 2 dilution distribution has been found to have a negligible impact on the outcomes observed, as it was dominated by the effects arising from turbulence intensity, nature of initial CO 2 distribution and integral length scale of CO 2 dilution.
“…Interest in alternative fuel solutions has increased over the years, and the transportation industry and governments are making a concerted effort to move to renewable and eco-friendly solutions to meet ever more stringent emissions and pollution standards (Patterson et al, 2011;Mustafi et al, 2020;Koonaphapdeelert et al, 2020;Korberg et al, 2020;Rafiee et al, 2021). Despite electric vehicles being heralded as the future of the industry, the use of the internal combustion engine is expected to play a dominant role for the upcoming decades due to existing investment in such technologies along with its widespread use.…”
The localised forced ignition and subsequent flame propagation have been analysed for stoichiometric biogas-air mixtures (CH 4 /CO 2 /air blend) with different spatial distributions (uniform, Gaussian and bimodal) and mean levels of CO 2 dilution (i.e. mole fraction of CO 2 ) for different flow conditions (e.g. quiescent laminar condition and different turbulence intensities) using three-dimensional Direct Numerical Simulations. A two-step chemical mechanism with sufficient accuracy is used to capture the effects of CO 2 dilution on the laminar burning velocity of the biogas − air mixture. A parametric analysis in terms of the mean, standard deviation and integral length scale of the initial Gaussian and bimodal distributions of spatial CO 2 dilution in the unburned gas has been conducted. Qualitatively similar behaviour has been observed for all three initial spatial distributions of CO 2 . A departure from uniform conditions was found to increase the range of reaction rate magnitudes of CH 4 , which impacts the burned gas volume and, in turn, increases the variability of the outcomes of the ignition event (successful thermal runaway and subsequent self-sustained propagation or misfire). Turbulence intensity and the mean level of dilution were found to have significant impacts on the outcome of the localised forced ignition, and an increase of either quantity acts to reduce the burned gas volume irrespective of mixture composition due to the enhancement of heat transfer from the hot gas kernel, and the heat sink effects of CO 2 , respectively. An increase of the integral length scale 𝑙 𝜓 for the spatial distribution of CO 2 dilution increased the probability of a successful outcome of the ignition event. A uniform initial spatial distribution was found to be optimal, and in the case of a departure from nonuniform conditions, larger variability in the outcome are obtained for a Gaussian initial distribution of CO 2 dilution than a bimodal one. The variance of the CO 2 dilution distribution has been found to have a negligible impact on the outcomes observed, as it was dominated by the effects arising from turbulence intensity, nature of initial CO 2 distribution and integral length scale of CO 2 dilution.
“…Anaerobic digestion (AD) is a biological process where solid organic matter originated in the agriculture and livestock industry, among others, is used to obtain biogas containing methane (CH 4 ), which in quantities of~65% is burned to produce bioenergy as heat and electricity in cogeneration engines [1]. The world's biggest waste sources used in AD come from rice farming, corn farming, and wheat.…”
Section: Introductionmentioning
confidence: 99%
“…Among them, the major energy crops for biogas production are maize silage and grass, followed by lignocellulosic residues or other plant biomass in general (rich in lignin content) from sources such as banana plants (leftover banana trees, flowers, leaves), palm oil residues after harvest, sugar and palm oil refinement processes (that produce large quantities of fibrous lignocellulosic biomass), forestry residues, coffee pulp, and field residues such as corn stover [2]. AD is conducted by breaking up the organic matter (anaerobically) generating biogas, mainly composed of methane (CH 4 ) and carbon dioxide (CO 2 ), with a lower concentration of hydrogen sulphide (H 2 S), ammonium (NH 3 ), and other trace compounds [1].…”
Section: Introductionmentioning
confidence: 99%
“…AD is carried out by several groups of bacteria and methanogenic archaea in four stages: hydrolysis, acidogenesis, acetogenesis, and methanogenesis, CH 4 is produced in the last stage [1]. In the intermediate stages of AD, H 2 S is produced from the degradation of proteins containing sulphur-rich amino acids and from the sulphate reduction (SO 4 2− ).…”
Section: Introductionmentioning
confidence: 99%
“…Biofilters for gas treatment are devices in which a residual gas current containing pollutants is passed through a packing material containing bacteria immobilized as biofilms capable of metabolizing the pollutants (like H 2 S in biogas) [15]. There are two groups of biofilters: (1) open biofilters: usually a box with packing material containing the biofilms inside which is open to the atmosphere, in which parameters such as temperature, humidity, and the purity of the microbial cultures are difficult to control as they are weather dependent (due to rain and temperature fluctuation, among others); and (2) closed biofilters: in which the biofilmcontaining packing material is inside a closed container (usually made of steel or plastic), making it easier to control parameters such as culture media flow, nutrients, gas flow, temperature, and humidity [16]. Biofiltration is considered more environmentally and economically friendly than physical-chemical methods, as it requires significantly lower chemical use and energy consumption, which translates into a low carbon footprint and lower costs [14].…”
The agriculture and livestock industry generate waste used in anaerobic digestion to produce biogas containing methane (CH4), useful in the generation of electricity and heat. However, although biogas is mainly composed of CH4 (~65%) and CO2 (~34%), among the 1% of other compounds present is hydrogen sulphide (H2S) which deteriorates engines and power generation fuel cells that use biogas, generating a foul smell and contaminating the environment. As a solution to this, anoxic biofiltration, specifically with biotrickling filters (BTFs), stands out in terms of the elimination of H2S as it is cost-effective, efficient, and more environmentally friendly than chemical solutions. Research on the topic is uneven in terms of presenting performance markers, underestimating many microbiological indicators. Research from the last decade was analyzed (2010–2020), demonstrating that only 56% of the reviewed publications did not report microbiological analysis related to sulphur oxidising bacteria (SOB), the most important microbial group in desulphurisation BTFs. This exposes fundamental deficiencies within this type of research and difficulties in comparing performance between research works. In this review, traditional and microbiological performance markers of anoxic biofiltration to remove H2S are described. Additionally, an analysis to assess the efficiency of anoxic BTFs for biogas desulphurisation is proposed in order to have a complete and uniform assessment for research in this field.
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