2016
DOI: 10.1016/j.copbio.2015.12.018
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Biomass pretreatments capable of enabling lignin valorization in a biorefinery process

Abstract: Recent techno-economic studies of proposed lignocellulosic biorefineries have concluded that creating value from lignin will assist realization of biomass utilization into valuable fuels, chemicals, and materials due to co-valorization and the new revenues beyond carbohydrates. The pretreatment step within a biorefinery process is essential for recovering carbohydrates, but different techniques and intensities have a variety of effects on lignin. Acidic and alkaline pretreatments have been shown to produce div… Show more

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Cited by 110 publications
(61 citation statements)
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References 74 publications
(54 reference statements)
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“…Vanillin, 4‐hydroxybenzaldehyde, and syringaldehyde are typical representatives of the G, H, and S group in lignin, respectively, and these inhibitors generated from pretreatment would precipitate the enzymes, hampering hydrolysis and fermentation . Several Trichoderma species have alternative enzyme systems commonly seen in other organisms, such as multicooper laccase peroxidases and dioxygenase, which make it possible to degrade phenolics.…”
Section: Resultsmentioning
confidence: 99%
“…Vanillin, 4‐hydroxybenzaldehyde, and syringaldehyde are typical representatives of the G, H, and S group in lignin, respectively, and these inhibitors generated from pretreatment would precipitate the enzymes, hampering hydrolysis and fermentation . Several Trichoderma species have alternative enzyme systems commonly seen in other organisms, such as multicooper laccase peroxidases and dioxygenase, which make it possible to degrade phenolics.…”
Section: Resultsmentioning
confidence: 99%
“…It is worth to point out that, due to real possibilities to obtain valuable by‐products from lignin treatments using modern industrial processes, most of techno‐economic works reported in literature about lignin valorization have been aimed to assess new delignification techniques or ways to obtain especial chemical compounds . This seems to be the main reason by which similar studies focused on the use of lignin as fuel are very scarce, being almost exclusively linked to the pulp and paper industry .…”
Section: Resultsmentioning
confidence: 99%
“…The high number of papers that cover lignin valorization, which have been identified by this work, introduces the research advances in the whole processing: the improvements in isolation, recovery, and characterization of lignin from biomass, the posterior depolymerization of lignin into monomers by chemical and biological means, and the final upgrading of the depolymerized lignin monomers to industrially relevant chemicals [41]. All these aspects have been deeply described by several reviews [42][43][44][45][46][47][48][49][50][51][52][53][54][55][56][57], and, therefore, the purpose of this section is just to summarize the most The most frequently selected keyword was Lignin, with 245 appearances. As Lignin was one of the words employed in the search engine, it is quite logical to find it among the most common keywords.…”
Section: Review Of the Main Alternatives For Lignin Valorization And mentioning
confidence: 95%