Abstract:The article presents an analysis of the possibilities of biogas production in the process of methane fermentation of sonicated excess sludge. The greater the percentage of methane in biogas, the higher its calorific value. In order to increase the intensity of biogas production containing approximately 70% of methane, sewage sludge is disintegrated. In particular, excess sludge formed as a result of advanced wastewater treatment by the activated sludge method shows low biodegradability. The study aim was to ex… Show more
“…The biogas produced contains 60 -78% of methane with an average of 74%. This percentage of methane in biogas is similar to the percentage reported by Zawieja et al [44]. In fact, these researchers reported a higher percentage of 77% of methane in the biogas produced from sonicated excess sludge.…”
A great amount of wastewater is generated each day from the slaughterhouse located in the harbor area (Togo). This amount of wastewater is a source of environmental pollution and degradation of water quality, as it is discharged with no treatment. The wastewater produced by slaughterhouses is biodegradable with a ratio between biological oxygen demand (BOD5) and chemical oxygen demand (COD) (BOD5/COD) > 0.5. Anaerobic co-digestion was used in this study to assess the bio-energy potential and kinetics of biogas production during processing. An effective anaerobic digestion design shows that over 90% of organic material was removed when inoculation and the carbon/nitrogen (C/N) ratio were adjusted. Biogas production was significantly affected by COD concentration, inoculation and C/N ratio. The cumulative volume of biogas increased from 415 mL to 2,150 mL as the substrate/inoculum (S/I) ratio has decreased from 2.028 to 0.337, while the cumulative volume of biogas increased from 1,140 mL to 5,250 mL as the C/N ratio increased from 6 to 22. The biogas produced has a high calorific value, as the methane content is 74% after simple purification with a concentrated solution of NaOH. Among the three kinetic models used to describe biogas production, a modified Gompertz model was found to be the best with R2 between 0.983 and 0.993. Then, the logistical model with R2 between 0.902 and 0.928 and the first order kinetic model with R2 between 0.552 and 0.704
“…The biogas produced contains 60 -78% of methane with an average of 74%. This percentage of methane in biogas is similar to the percentage reported by Zawieja et al [44]. In fact, these researchers reported a higher percentage of 77% of methane in the biogas produced from sonicated excess sludge.…”
A great amount of wastewater is generated each day from the slaughterhouse located in the harbor area (Togo). This amount of wastewater is a source of environmental pollution and degradation of water quality, as it is discharged with no treatment. The wastewater produced by slaughterhouses is biodegradable with a ratio between biological oxygen demand (BOD5) and chemical oxygen demand (COD) (BOD5/COD) > 0.5. Anaerobic co-digestion was used in this study to assess the bio-energy potential and kinetics of biogas production during processing. An effective anaerobic digestion design shows that over 90% of organic material was removed when inoculation and the carbon/nitrogen (C/N) ratio were adjusted. Biogas production was significantly affected by COD concentration, inoculation and C/N ratio. The cumulative volume of biogas increased from 415 mL to 2,150 mL as the substrate/inoculum (S/I) ratio has decreased from 2.028 to 0.337, while the cumulative volume of biogas increased from 1,140 mL to 5,250 mL as the C/N ratio increased from 6 to 22. The biogas produced has a high calorific value, as the methane content is 74% after simple purification with a concentrated solution of NaOH. Among the three kinetic models used to describe biogas production, a modified Gompertz model was found to be the best with R2 between 0.983 and 0.993. Then, the logistical model with R2 between 0.902 and 0.928 and the first order kinetic model with R2 between 0.552 and 0.704
“…During anaerobic digestion, more dissolved hydrolysate will provide more nutrient substrate for acidification and produce more VFAs . As shown in Figure , with the progress of anaerobic fermentation acid production, the total concentration of VFAs increases with time and shows a trend of increasing first and then decreasing.…”
To investigate the
dissolution characteristics of low-temperature
thermal pretreatment conditions and the process of sludge fermentation
to produce acid, the influence of thermal pretreatment temperature
on the dissolution of excess sludge organic composition and the mechanism
of cell crushing of sludge thermal pretreatment were analyzed by an
experimental method, and the performance of acid production was explored
by sludge fermentation after pretreatment at different temperatures.
The performance of acid production by sludge fermentation after pretreatment
at different temperatures was measured. The results proved that the
soluble chemical oxygen demand (SCOD) shows the largest increase in
dissolution rate (11.92%) at 70 °C and in dissolution quantity
(6518.33 mg/L) at 90 °C. However, at 80 °C, the solubility
of total organic carbon (TOC) is the highest (3224.47 mg/L), and at
70 °C, the best dissolution conditions for soluble carbohydrate
(SC) and soluble protein (SP) reached 340.07 and 80.92 mg/L, respectively.
The degree of sludge breaking starts to increase at 70 °C. Correlation
analysis shows that dissolved organic matter is mainly derived from
the cell wall and intracellular material and SP is mainly derived
from intracellular material. Excitation–emission matrix spectra
and parallel factor analysis (EEM-PARAFAC) divides the sludge dissolved
organic matter (DOM) into five fluorescent components, including C1
(318/366) tyrosine, C2 (418/470) UVA humic acid, C3 (282/334) tryptophan
substances, C4 (322/430) UVC humic acids, and C5 (314, 382, 454/526)
UVA humic substances. Fermentation acid production experiment shows
that the peak concentration is highest at 80 °C, the arrival
time is 2 days, and the acid production type is butyric acid fermentation.
Thus, it is proved that low-temperature thermal pretreatment promotes
the process of acid-producing fermentation and has no effect on the
type of fermentation. The optimal condition for hydrolytic dissolution
and acid production under low-temperature thermal pretreatment is
80 °C.
“…Pretreatment of sludge with ultrasonic frequencies has been shown to significantly enhance the disintegration of the sludge, and thereby accelerate anaerobic digestion [49][50][51]. However, attenuation of sound is proportional to the sound's frequency.…”
Section: Sonic Treatment Of Anaerobic Digestatementioning
confidence: 99%
“…Used as a pretreatment for the disintegration of sludge prior to anaerobic digestion, ultrasonication can vary considerably in duration and intensity. For instance, Zawiega found an intensity of 4.3 W cm −2 for 300 s to be optimal for solubilizing WAS in treating 0.5 L sludge samples prior to digestion in a 5 L reactor for 28 d [49]. Assuming that the WAS sample was diluted to a volume of 5 L, this represents a power input of 2580 J L −1 of WAS.…”
Section: Sonic Treatment Of Anaerobic Digestatementioning
Wastewater created from various solid wastes and agricultural residues was treated by anaerobic digestion, and the biogas and wastewater odors were quantified. One digester was exposed to low-frequency sound (<5 kHz) from underwater loudspeakers, while the other received no sonic treatment. It was hypothesized that low-frequency sound, by accelerating the breakdown of sludge via mechanisms such as cavitation induction and mechanical vibration, and enhancing biogas production, could also affect the concentrations of wastewater odors. During warm seasons, biogas production from the sound-treated digester was 29% higher than that from the control digester, and 184% higher during the cool season. Malodors—Mainly consisting of typical aromatic malodorants such as p-cresol and skatole, aliphatic secondary ketones, and dimethyl disulfide—were quantified. In contrast to the findings for biogas production, little difference was found in the concentrations of volatile compounds in the control and sound-treated digestates. Concentrations of dimethyl polysulfides increased over time in both the control and sound-treated digestates, likely due to the use of recycled system effluent that contained precipitated elemental sulfur. The digestate contained considerable concentrations of volatile fatty acids and ammonium, but due to the near neutral pH of the digestate it was surmised that neither made appreciable contributions to the wastewater’s malodor. However, the volatile fatty acid concentrations were reduced by sonic treatment, which was not unexpected, since volatile fatty acids are precursors to methane. Therefore, although sonic treatment of the anaerobic digestate boosted biogas production, it did not markedly affect the wastewater malodors. The biosynthetic origins of wastewater malodors are discussed in this paper.
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