“…This constrains include the electrolyte resistance (ohmic), the charge-transfer resistance due to slow reaction rates on electrodes (kinetic), and the resistance caused by retarded diffusion (transport) [121]. This limitations result in low power densities and coulombic efficiencies that range between 9 to 72 mW m -2 and 0.05-10.48% [109].…”
Section: Challenges and Future Perspectives For Cw-mfc Systemsmentioning
confidence: 99%
“…Additional limiting factors that must be considered include i) the internal resistance of a CW-MFC which increases linearly as the size and distance between electrodes increase [24]; ii) the over-potential during activation and the insufficient electrical contact between bacteria and anode [122]; iii) the competition between EAB and other microorganisms (e.g. methanogenic bacteria) for electrons or substrates leading to low coulombic efficiencies [109]; iv) the deterioration of cathode over time and the excessive growth of heterotrophic bacteria around it that plummet the concentrations of electron acceptors like O2 [114]; as well as v) the high concentration of organic matter that could increase slightly the acidity inside the systems, limiting the growth of EAB and the diffusion of protons, therefore affecting the coulombic efficiency [113].…”
Section: Challenges and Future Perspectives For Cw-mfc Systemsmentioning
28Also, the adoption of those principles for the development of MET set-ups for simultaneous 29 wastewater treatment and power generation, and the challenges that the technology face.
30Ultimately, the most recent developments in set-ups that merges MET with constructed wetlands 31 are presented and discussed.
“…This constrains include the electrolyte resistance (ohmic), the charge-transfer resistance due to slow reaction rates on electrodes (kinetic), and the resistance caused by retarded diffusion (transport) [121]. This limitations result in low power densities and coulombic efficiencies that range between 9 to 72 mW m -2 and 0.05-10.48% [109].…”
Section: Challenges and Future Perspectives For Cw-mfc Systemsmentioning
confidence: 99%
“…Additional limiting factors that must be considered include i) the internal resistance of a CW-MFC which increases linearly as the size and distance between electrodes increase [24]; ii) the over-potential during activation and the insufficient electrical contact between bacteria and anode [122]; iii) the competition between EAB and other microorganisms (e.g. methanogenic bacteria) for electrons or substrates leading to low coulombic efficiencies [109]; iv) the deterioration of cathode over time and the excessive growth of heterotrophic bacteria around it that plummet the concentrations of electron acceptors like O2 [114]; as well as v) the high concentration of organic matter that could increase slightly the acidity inside the systems, limiting the growth of EAB and the diffusion of protons, therefore affecting the coulombic efficiency [113].…”
Section: Challenges and Future Perspectives For Cw-mfc Systemsmentioning
28Also, the adoption of those principles for the development of MET set-ups for simultaneous 29 wastewater treatment and power generation, and the challenges that the technology face.
30Ultimately, the most recent developments in set-ups that merges MET with constructed wetlands 31 are presented and discussed.
“…This constraint includes the electrolyte resistance (ohmic), the charge-transfer resistance due to slow reaction rates on electrodes (kinetic), and the resistance caused by retarded diffusion (transport) [123]. These limitations result in low power densities, and coulombic efficiencies that range between 9 to 72 mW m −2 and 0.05-10.48% [111].…”
Section: Challenges and Future Perspectives For Cw-mfc Systemsmentioning
confidence: 99%
“…Additional limiting factors that must be considered include i) the internal resistance of a CW-MFC, which increases linearly as the size and distance between electrodes increase [24]; ii) the over-potential during activation and the insufficient electrical contact between bacteria and anode [124]; iii) competition among EAB and other microorganisms (e.g., methanogenic bacteria) for electrons or substrates leading to low coulombic efficiencies [111]; iv) the deterioration of the cathode over time, and the excessive growth of heterotrophic bacteria around it that make the concentrations of electron acceptors like O 2 plummet [116]; as well as v) the high concentration of organic matter that could slightly increase the acidity inside the systems, limiting the growth of EAB and the diffusion of protons, and therefore affecting the coulombic efficiency [115].…”
Section: Challenges and Future Perspectives For Cw-mfc Systemsmentioning
Microbial electrochemical technologies (MET) rely on the presence of the metabolic activity of electroactive bacteria for the use of solid-state electrodes for oxidizing different kinds of compound that can lead to the synthesis of chemicals, bioremediation of polluted matrices, the treatment of contaminants of interest, as well as the recovery of energy. Keeping these possibilities in mind, there has been growing interest in the use of electrochemical technologies for wastewater treatment, if possible with simultaneous power generation, since the beginning of the present century. In the last few years, there has been growing interest in exploring the possibility of merging MET with constructed wetlands offering a new option of an intensified wetland system that could maintain a high performance with a lower footprint. Based on that interest, this paper explains the general principles of MET, and the different known extracellular electron transfer mechanisms ruling the interaction between electroactive bacteria and potential solid-state electron acceptors. It also looks at the adoption of those principles for the development of MET set-ups for simultaneous wastewater treatment and power generation, and the challenges that the technology faces. Ultimately, the most recent developments in setups that merge MET with constructed wetlands are presented and discussed.
“…MFCs require the anode in anaerobic zones whereas the cathode needs oxygen; both redox conditions naturally occur inside CWs. For [185]. But electrobioremediation can also be merged with other mitigation approaches, such as: -Incorporating selected plants could prevent CH 4 and N 2 O production by the system [174].…”
This review describes a new means of control and stimulation of microorganisms involved in the bioremediation of sediments and waterlogged soils. This emerging technology is derived from sedimentary microbial fuel cells, and consists in ensuring aerobic respiration of aerobic microbial populations in anaerobic conditions by means of a fixed potential anode in order to evacuate the electrons coming from the microbial respiratory chains. This review describes the conceptual basis of the electro-bioremediation, the material devices used (electrode set-ups and spacing), and finally studies the various devices published since the bench tests until the scarce in-field implementations.
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