Biodiesel production from Jatropha curcas L. oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions

Abstract

Please cite this article as: Siow Hwa Teo, Motonobu Goto, Yun Hin Taufiq-Yap, Biodiesel production from Jatropha curcas L.oil with Ca and La mixed oxide catalyst in near supercritical methanol conditions, The Journal of Supercritical Fluids http://dx. AbstractThe catalytic transesterification of crude Jatropha curcus oil (JCO) with supercritical methanol (scMeOH), in the presence of calcium lanthanum mixed oxide (CaLaO) heterogeneous base catalyst was carried out using a batch reactor at near critical temperatures and pressures. The performance of synthesized CaLaO mixed oxide catalysts was examined by characterizing it through instruments such as XRD, BET and CO 2 -TPD, revealed that the Ca/La atomic ratio strongly affects the phase structure, catalyst basic sites, and thus the catalytic reactivity. The reaction parameters including Ca/La atomic molar ratio in the mixed metal oxide catalyst, molar ratio of methanol to oil, catalyst concentration, reaction pressure, temperature and time were varied one at a time and optimized based on the content of fatty acid methyl esters (FAMEs). The highest FAME yield for supercritical methanolysis reached 93 % under the optimum reaction conditions: 240 ○ C, 8.2 MPa, a molar ratio of methanol to oil of 21:1, and reaction time of 60 min in the presence of 1 wt. % catalyst. The results demonstrated that the presence of CaLaO mixed oxide catalyst in the reaction system effectively reduced reaction temperature, time and pressure of supercritical conditions. It required a very low concentration to mitigate the harsh operation conditions (290 ○ C, 15 MPa, 60 min) of the scMeOH process. On the other hand, supercritical reaction compensated for low conversion rate of solid catalytic transesterification whereby, it takes one step further byimproving the role of catalyst with supercritical conditions to achieve higher yield and shorter processing time. The reusability of CaLaO mixed oxide catalyst for repeated use was tested, the catalytic activity was >80 % when the catalyst was employed for fourth time. The study concluded that slight leaching of Ca 2+ (0.52~6.07 ppm) and La 3+ (0.34~2.33 ppm) occurred during transesterification reaction, however it is below acceptable levels of metals as ASTM D6751 (United State) and in Europe, EN 14214 (Europe) standards. This proved that heterogeneous catalytic supercritical reaction process is more promising than non-catalytic processes and it can be turned to practical use in the near future.

Evaluation of La-Doped CaO Derived from Cockle Shells for Photodegradation of POME

“…Besides, the diffraction peaks of La/CaO in Figure 1 shows the peaks shifted to lowest 2θ due to lattice expansion [44] which indicated the incorporation of La ion into CaO lattice structure. Meanwhile, the small peak approximately around 2θ = 30° in 1 wt%, 3 wt%, and 5 wt% La/CaO were detected to be lanthanum oxide [45,46]. The XRD patterns for all the La/CaO samples show the absence of lanthanum carbonate as shown in Figure 1(b), (c), and (d).…”

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Synthesis and characterization of solid heterogeneous catalyst for the production of biodiesel from high FFA waste cooking oil

“…Brunauer-Emmet-Teller (BET) surface area , pore volume and pore size distribution of the synthesized catalysts were measured from the multi-point nitrogen adsorption-desorption isotherms (at -196 °C) using a micrometrics ASAP 2020 3Flex version 1.02 (Siow et al 2015).…”