Biocatalytic Ether Lipid Synthesis by an Archaeal Glycerolprenylase
Felix Kaspar,
Lea Eilert,
Sophie Staar
et al.
Abstract:Although ethers are common in secondary natural products, they are an underrepresented functional group in primary metabolism. As such, there are comparably few enzymes capable of constructing ether bonds in a general fashion. However, such enzymes are highly sought after for synthetic applications as they typically operate with higher regioselectivity and under milder conditions than traditional organochemical approaches. To expand the repertoire of well characterized ether synthases, we herein report on a pr… Show more
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