Biobased supramolecular ionic networks with optimized crystallinity and mechanical properties as promising dynamic materials for eutectogels design

Ronco, L.I.; Luque, G.C.; Calderón, C. Andrea; Euti, E.M.; Fiori, E. Rufeil; Barraco, Daniel E.; Leiva, E.P.M.; Mecerreyes, David; Minari, R.J.; Picchio, Matías L.

doi:10.1016/j.mtchem.2023.101525

Cited by 3 publications

(3 citation statements)

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“…The field of eutectogels has proliferated over the last few years, although the main focus has been placed on bioelectronic and energy storage applications because of the intrinsic ionic nature of DES. [64][65][66] In addition, some recent works have proposed eutectogels from therapeutic deep eutectic solvents (THEDES), where at least one component is an active pharmaceutical ingredient. [67][68][69][70] There is still much to be done in this emerging topic, principally expanding the application of eutectogels to other areas.…”

Section: Enzyme Immobilization In Eutectogelsmentioning

confidence: 99%

“…in 2018 to describe the embedment of a Li + ‐conducting DES within a silica matrix, [63] although now it is broadly used to define any gel in which the swelling agent is a traditional eutectic solvent or a DES. The field of eutectogels has proliferated over the last few years, although the main focus has been placed on bioelectronic and energy storage applications because of the intrinsic ionic nature of DES [64–66] . In addition, some recent works have proposed eutectogels from therapeutic deep eutectic solvents (THEDES), where at least one component is an active pharmaceutical ingredient [67–70] .…”

Section: Enzyme Immobilization In Eutectogelsmentioning

confidence: 99%

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Eutectogels as Promising Materials in Biocatalysis

Kumar,

Calderón,

Beloqui

et al. 2024

ChemCatChem

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The entrapment of deep eutectic solvents (DES) and eutectic systems into porous scaffolds renders a new class of soft and nonvolatile materials called eutectogels that have recently stepped into the spotlight in different areas ranging from electronics to drug delivery. Recent progress in the use of DES in biocatalysis, where they have been demonstrated to improve substrate supply, conversion, and enzyme stability, has opened an unparalleled opportunity to exploit the merits of eutectogels for immobilizing biological catalysts. The resulting functional materials could outperform traditional hydrogels and ionic liquid gels, offering fresh perspectives to broaden the application scope of many enzymes. In this perspective, we go into the potential of eutectogels as innovative scaffolds that support biocatalytic reactions and discuss different applications where these systems could show plain benefits compared to traditional materials. Future directions for this newly developed technology are highlighted.

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Section: Enzyme Immobilization In Eutectogelsmentioning

confidence: 99%

Section: Enzyme Immobilization In Eutectogelsmentioning

confidence: 99%

Eutectogels as Promising Materials in Biocatalysis

Kumar,

Calderón,

Beloqui

et al. 2024

ChemCatChem

Self Cite

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“…20,25,26 Simultaneously, researchers like Ronco et al have utilized reversible hydrogen bond networks between polymers and DES to impart self-healing and strong adhesion properties to gels, enabling them to serve as electrolytes for lithium batteries, further expanding the application scope of DES gels. 27…”

Section: Introductionmentioning

confidence: 99%