Bio-inspired asymmetric aldehyde arylations catalyzed by rhodium-cyclodextrin self-inclusion complexes

Tsuda, S.; Asahi, Kaoru; Takahashi, Ryota; Yamauchi, Hiroki; Ueda, Ryoji; Iwasaki, Takanori; Fujiwara, Sayaka; Kambe, Nobuaki

doi:10.1039/d1ob02014e

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2023

Publication Types

Select...

Article1

Book1

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

References 48 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Halogen‐Substituted Mesoionic‐Carbene/Palladium Complexes for Catalytic Arylation of Aldehydes

et al. 2023

View full text Add to dashboard Cite

Various halogenated mesoionic‐carbene (MIC)‐coordinated palladium complexes (denoted as TAPs and e‐TAPs) were prepared using triazolylidene precursors that were synthesized in only two steps via a click reaction. Among the prepared complexes, 2‐Bromophenyl group substituted e‐TAP (Br‐e‐TAP) showed optimal catalytic activity for the arylation of aldehydes with arylboronic compounds. Additionally, the Br‐e‐TAP catalyst assisted in synthesizing a wide range of functionalized diarylmethanols and arylmethanols in 29–95% yields with loadings of 0.2–0.6 mol% Pd.

show abstract