Binuclear isophthaloylbis(N,N-diphenylthioureate) transition metal complexes: Synthesis, spectroscopic, thermal and structural characterization

Ammonium‐Iron(III) metallacryptate inclusion complexes based on Aroylbis(N,N‐diethylthioureas): Synthesis and structure

“…The last four decades witnessed a wide exploration in the coordination chemistry of aroylthioureas, which mainly focuses on the metal complexes of the basic benzoyl(N,N-dialkylthioureas) HL I , [1][2][3][4][5][6][7][8][9] and the bipodal iso-phthaloylbis(N,N-dialkylthioureas) H2L II (figure 1). [10][11][12][13][14][15] In most of structurally determined complexes, aroylthiourea moieties deprotonate and form bidentate (S,O)-chelators (figure 1).…”

“…Figure 1: Mono-and bi-podal aroylthioureas and their metal complexes [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15] Recently, novel bipodal aroylbis(thioureas) incorporating modified aromatic spacers such as pyridine (H2L 1 ) and catechol (H2L 2 ) have been developed. They offer completely different coordination abilities.…”

Crystal structure, Hirshfeld surface analysis, and DFT studies of N-(2-chlorophenylcarbamothioyl)cyclohexanecarboxamide

“…Among these, the Nbenzoyl thiourea derivatives are versatile ligands that coordinate to form stable compounds. These derivatives possess very strong donor groups (Carbonyl and thioamide) that allow the preparation of different transition metal complexes, either monoanionic bidentate form by deprotonation that forms neutral homoleptic or heteroleptic complexes with S,O coordination or in neutral form only through the S atom [3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20][21]. Several benzoyl thiourea derivatives and their metal complexes are also associated with various types of biological activities such as insecticidal, herbicidal, antibacterial, antifungal, anti-tubercular, antithyroid, anthelmintic, rodenticidal, and plant growth regulator properties [22][23][24][25].…”