Binder-Free Electrode Based on ZnO Nanorods Directly Grown on Aluminum Substrate for High Performance Supercapacitors

Ahmed, Faheem; Almutairi, Ghzzai; AlOtaibi, Bandar; Kumar, Shalendra; Arshi, Nishat; Hussain, Syed Ghazanfar; Ahmad, Naushad; Aljaafari, Abdullah

doi:10.3390/nano10101979

Cited by 24 publications

(6 citation statements)

References 49 publications

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“…The crystallite size, determined from the pattern using Scherrer's formula, was found to be in the range of 5.59-10.25 nm. R spectra revealed F2g active modes corresponding to the Ce-O8 vibrational units of The UV-Vis spectra were found to exhibit a strong broadband between 200-800 nm V − I(V)dV, where m (g) denotes the mass of the active material and k (V s −1 ) is scan rate, C (F g −1 ) represents the specific capacitance, and I (A) symbolizes the discharge current [31]. The values of the specific capacitance of CeO 2 , Ce 0.98 F 0.02 O 2 , and Ce 0.78 Fe 0.02 Cu 0.20 O 2 electrodes (see Figure 7b), determined using the CV curve at the scan rate of 10 mV s −1 , were 487.0 F g −1 , 532.8 F g −1 , and 488.0 F g −1 , respectively.…”

Section: Discussionmentioning

confidence: 99%

Influence of Fe and Cu Co-Doping on Structural, Magnetic and Electrochemical Properties of CeO2 Nanoparticles

et al. 2022

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The nanoparticles of CeO2, Ce0.98Fe0.02O2, and Ce0.78Fe0.02Cu0.20O2 were synthesized using the co-precipitation-synthesis technique. The effect of co-doping of Fe and Cu on structural, optical, and magnetic properties as well as specific capacitance have been studied using X-ray diffraction (XRD), scanning-electron microscopy (SEM), UV-visible spectroscopy, Raman spectroscopy, dc magnetization, and electrochemical measurements at room temperature. The results of the XRD analysis infer that all the samples have a single-phase nature and exclude the formation of any extra phase. Particle size has been found to reduce as a result of doping and co-doping. The smallest particle size was obtained to be 5.59 nm for Ce0.78Fe0.02Cu0.20O2. The particles show a spherical-shape morphology. Raman active modes, corresponding to CeO2, were observed in the Raman spectra, with noticeable shifting with doping and co-doping indicating the presence of defect states. The bandgap, calculated using UV-Vis spectroscopy, showed relatively low bandgap energy (1.7 eV). The dc magnetization results indicate the enhancement of the magnetic moment in the samples, with doping and co-doping. The highest value of saturation magnetization (1.3 × 10−2 emu/g) has been found for Ce0.78Fe0.02Cu0.20O2 nanoparticles. The electrochemical behavior studied using cyclic-voltammetry (CV) measurements showed that the Ce0.98Fe0.02O2 electrode exhibits superior-specific capacitance (~532 F g−1) along with capacitance retention of ~94% for 1000 cycles.

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Section: Discussionmentioning

confidence: 99%

Influence of Fe and Cu Co-Doping on Structural, Magnetic and Electrochemical Properties of CeO2 Nanoparticles

et al. 2022

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“…After 2000 cycles, a slight increase in the ESR value of about 2.70 Ω was observed. Furthermore, no distinct semicircle was observed in EIS spectra, which implies that the 5%-Cr-doped BiFeO 3 electrode exhibits excellent capacitive behavior [50,51]. magnetic interactions caused by Fe 3+ -O-Cr 3+ coupling.…”

Section: Electrochemical Analysismentioning

confidence: 92%

Role of Cr Doping on the Structure, Electronic Structure, and Electrochemical Properties of BiFeO3 Nanoparticles

et al. 2022

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BiFe1−xCrxO3, (0 ≤ x ≤ 10) nanoparticles were prepared through the sol–gel technique. The synthesized nanoparticles were characterized using various techniques, viz., X-ray diffraction, high-resolution field emission scanning electron microscopy (HRFESEM), energy dispersive spectroscopy (EDS), UV–Vis absorption spectroscopy, photoluminescence (PL), dc magnetization, near-edge X-ray absorption spectroscopy (NEXAFS) and cyclic voltammetry (CV) measurements, to investigate the structural, morphological, optical, magnetic and electrochemical properties. The structural analysis showed the formation of BiFeO3 with rhombohedral (R3c) as the primary phase and Bi25FeO39 as the secondary phase. The secondary phase percentage was found to reduce with increasing Cr content, along with reductions in crystallite sizes, lattice parameters and enhancement in strain. Nearly spherical shape morphology was observed via HRFESEM with Bi, Fe, Cr and O as the major contributing elements. The bandgap reduced from 1.91 to 1.74 eV with the increase in Cr concentration, and PL spectra revealed emissions in violet, blue and green regions. The investigation of magnetic field (H)-dependent magnetization (M) indicated a significant effect of Cr substitution on the magnetic properties of the nanoparticles. The ferromagnetic character of the samples was found to increase with the increase in the Cr concentration and the increase in the saturation magnetization. The Fe (+3/+4) was dissolved in mixed-valence states, as found through NEXAFS analysis. Electrochemical studies showed that 5%-Cr-doped BFO electrode demonstrated outstanding performance for supercapacitors through a specific capacitance of 421 F g−1 measured with a scan rate of 10 mV s−1. It also demonstrated remarkable cyclic stability through capacitance retention of >78% for 2000 cycles.

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“…Moreover, the density of Al is much lower than that of other metal substrates, which is beneficial to decrease the total mass of the energy storage devices. In recent years, many Al-based self-supporting electrode materials have been prepared by hydrothermal reactions [ 15 ], CVD [ 25 , 27 ], wet chemical methods [ 28 ], and so on, and possess high electrochemical performance. Therefore, Al substrates are promising candidates to prepare self-supporting electrode materials for the application of supercapacitors.…”

Section: Introductionmentioning

confidence: 99%

Al Foil-Supported Carbon Nanosheets as Self-Supporting Electrodes for High Areal Capacitance Supercapacitors

Zheng

Yan

et al. 2023

Molecules

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Self-supporting electrode materials with the advantages of a simple operation process and the avoidance of the use any binders are promising candidates for supercapacitors. In this work, carbon-based self-supporting electrode materials with nanosheets grown on Al foil were prepared by combining hydrothermal reaction and the one-step chemical vapor deposition method. The effect of the concentration of the reaction solution on the structures as well as the electrochemical performance of the prepared samples were studied. With the increase in concentration, the nanosheets of the samples became dense and compact. The CNS-120 obtained from a 120 mmol zinc nitrate aqueous solution exhibited excellent electrochemical performance. The CNS-120 displayed the highest areal capacitance of 6.82 mF cm−2 at the current density of 0.01 mA cm−2. Moreover, the CNS-120 exhibited outstanding rate performance with an areal capacitance of 3.07 mF cm−2 at 2 mA cm−2 and good cyclic stability with a capacitance retention of 96.35% after 5000 cycles. Besides, the CNS-120 possessed an energy density of 5.9 μWh cm−2 at a power density of 25 μW cm−2 and still achieved 0.3 μWh cm−2 at 4204 μW cm−2. This work provides simple methods to prepared carbon-based self-supporting materials with low-cost Al foil and demonstrates their potential for realistic application of supercapacitors.

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Binder-Free Electrode Based on ZnO Nanorods Directly Grown on Aluminum Substrate for High Performance Supercapacitors

Cited by 24 publications

References 49 publications

Influence of Fe and Cu Co-Doping on Structural, Magnetic and Electrochemical Properties of CeO2 Nanoparticles

Influence of Fe and Cu Co-Doping on Structural, Magnetic and Electrochemical Properties of CeO2 Nanoparticles

Role of Cr Doping on the Structure, Electronic Structure, and Electrochemical Properties of BiFeO3 Nanoparticles

Al Foil-Supported Carbon Nanosheets as Self-Supporting Electrodes for High Areal Capacitance Supercapacitors

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