“…Experimental results show that borate type compounds constitute a veritable source of NLO crystals with good nonlinear properties [7,8]. Therefore, all the recent NLO crystals discovered in the last 10 years are in majority borate based compounds such as: CsLiB 6 O 10 (CLBO), BiB 3 O 6 (BiBO), K 2 Al 2 B 2 O 7 (KABO), KBe 2 BO 3 F 2 (KBBF), ReCa 4 O(BO 3 ) 3 (Re = Gd, Y, La) -ReCOB [7][8][9][10][11][12][13], LnSc 3 (BO 3 ) 4 (Ln = lanthanide) [14,15], etc. Nowadays, two families of borate crystals are known that melt congruently or comprise congruently melting compounds, which can be grown in large sizes by the Czochralski method: the family of rare-earth calcium oxyborates with chemical composition ReCa 4 O(BO 3 ) 4 (Re being a rare -earth ion, usually Gd, Y or La) [16,17], and the family of LnSc 3 (BO 3 ) 4 borates.…”