Binary mixtures of 2-ethyl-1-hexanol with various functional groups (benzyl chloride, 3-methylaniline, 3-methoxyaniline and 2,6-dimethylcyclohexanone)

Abstract

In the binary mixtures of 2-ethyl-1-hexanol with various functional groups (benzyl chloride, 3-methyl aniline, 3-methoxy aniline and 2,6-dimethyl cyclohexanone) densities, speeds of sound and viscosities including those of pure liquids were measured over the entire composition range at different temperatures (303.15, 308.15 and 313.15) K and atmospheric pressure 0.1 MPa. Using this experimentally determined data, the excess/deviation parameters (molar volume, isentropic compressibility and deviation in viscosity) partial molar volumes, partial molar isentropic compressibilities of these components at infinite dilution were calculated. The results are discussed in terms of intermolecular forces between different component molecules in the binary mixture are more than the average intermolecular forces existing between the similar molecules of pure components.

Excellence in Acrylation – Scope and Limitation of Glucosyl Imidazolium‐coated Novozym 435 Catalyzed (Meth)acryl Ester Synthesis

“…Triple injections of approximately 10 μL volume for each sample were conducted with a 831 KF Coulometer from Metrohm. [99 % [8] ] [45] Acrylic acid 100 2 99.99 % (� 5.6) [50.1 %] [46] Acrylic acid 100 2 88.23 % (� 5.9) [~50 %] [38] Acrylic acid 250 2 99.99 % (� 2.3) [~99 %] [19] Acrylic acid / / / [c] [not found] Acrylic acid 500 5 83.89 % (� 0.7) [~60 %] [38] Acrylic acid 100 5 99.99 % (� 1.1) [66 %] [45] Acrylic acid 100 5 91.30 % (� 2.…”