Bimetallic Oxide of Y₂Cu₂O₅ for Electroreduction of CO₂ to Syngas

Abstract

The incorporation of guest elements into Cu-based bimetallic oxides has been proven as an effective way to modify the electronic structure and reactivity of Cu active sites. Here, the Y element was chosen as the guest element to modulate the electronic structure of Cu and alter its performance for electrochemical CO 2 reduction reaction (CO 2 RR). Y 2 Cu 2 O 5 , a high-crystallinity Cu-based bimetallic oxide, was synthesized via the sol−gel method. For pure-phase CuO and Y 2 O 3 controls, the selectivity of H 2 significantly exceeded that of CO. While Y and Cu combined in equal molar weights to form Y 2 Cu 2 O 5 , a notable enhancement in the CO selectivity was observed, resulting in a CO/H 2 ratio of approximately 1:1. These results prove that under the influence of Y, the electronic structure of Cu exhibits heightened CO selectivity. When the electrolyte solution was substituted with 1 M KOH, the CO/H 2 ratio achieved was about 2:1, indicating that the ratio of syngas can be adjusted by changing the concentration or type of electrolyte. This study explores the electronic modulation of a guest element in Cu-based bimetallic oxides and clarifies the beneficial influence of the Y element on the activity of Cu sites, which provides a novel approach for designing and regulating the activity of catalyst active sites.