Bimetallic multidimensional supramolecular coordination polymers containing triphenyltin cation and CuCN

Self-assembly and antitumor activity of an organotin coordination polymer containing a helical structure based on copper cyanide and phenanthroline ligand

“…When N-donor ligands are introduced into [CuCN]-based complexes, the result is a variety of coordination networks. However, to the best of our knowledge, few comprehensive studies of the [CuCN]-based complexes containing organometallic fragments are reported [23][24][25][26][27][28][29][30]. This limited number of structural motifs is known for [Cu m (CN) n -R 3 Sn-L] where L = bipodal organic ligand.…”

“…This limited number of structural motifs is known for [Cu m (CN) n -R 3 Sn-L] where L = bipodal organic ligand. This family of organotin polymers was considered as super-Prussianblue derivatives [31] which are related to zeolites that contain a rod-like anionic [CN·Sn (R 3 )-NC] − nanometer-sized spacer [23][24][25][26][27][28][29][30][31]. Helical structures have received special attention due to their potential applications in asymmetric catalysis, bioactivity, and nonlinear optical materials [32].…”

3D-Interpenetrating Frameworks of 3∞[Cu2(CN)4(Me3Pb)2(bpy)] Containing the Rhombic [Cu2(µ3-CN)2] Motifs

“…cations (R = Me or Ph) [1][2][3][4][5][6]. Because a single cyanide ligand can bridge two, three, or even four metal centers, it serves as an excellent network former.…”

Double Stranded Helical Organo-lead 3D-Supramolecular Coordination Polymer Containing Copper Cyanide and Phenanthroline Ligand as Antimicrobial Agent

“…The cyanide group plays a key role, since the cyanide group can stabilize a variety of transition metal centers. Recently, a large number of cyanide-bridged complexes with intriguing topologies and fascinating properties have been reported, among them, most important is the design and construction of cyanide-bridged heterometallic complexes [29][30][31][32][33][34][35][36]. When auxiliary N-donor ligands, like 1,10-phenanthroline (phen), 4,4 0 -bipyridine (4,4 0 -bpy) and pyrazine are introduced into [CuCN]-based complexes, the result is a variety coordination networks [37][38][39].…”