BCV spaces are a family of 3-dimensional Riemannian manifolds which include six of Thurston's eight geometries. In this paper, we give a complete classification of proper biharmonic Riemannian submersions from a 3-dimensional BCV space by proving that such biharmonic maps exist only in the cases ofIn each of these two cases, we are able to construct a family of infinitely many proper biharmonic Riemannian submersions.Our results on one hand, extend the results in [25] where a complete classification of proper biharmonic Riemannian submersions from a 3-dimensional space form was obtained, and on the other hand, can be viewed as the dual study of biharmonic surfaces (i.e., biharmonic isometric immersions) in a BCV space studied in [5,6,23,14].