Bifunctional Self-Penetrating Co(II)-Based 3D MOF for High-Performance Environmental and Energy Storage Applications

Abstract

A n e w m e t a l − o r g a n i c f r a m e w o r k , [Co 3 (BTC) 2 (Bimb) 3 (H 2 O) 2 ] n (KA@MOF-S), has been synthesized under hydrothermal conditions [H 3 BTC = 1,3,5-benzenetricarboxylic acid, Bimb = 1,4-bis[(1H-imidazol-1-yl)methyl]benzene] and characterized by singlecrystal X-ray diffraction (SC-XRD), elemental analysis, powder X-ray diffraction (PXRD), and Fourier-transform infrared spectroscopy (FT-IR).

Ligand Modulation on the Various Structures of Three Zinc(II)-Based Coordination Polymers for Antibiotics Degradation

“…The degradation of antibiotics did not significantly diminish when AO was added to the reaction, suggesting that h + was not the major active species either. However, the degradation of antibiotics was significantly inhibited by the addition of BQ and TBA, indicating that O 2 ˙ − and ˙OH played a crucial role [ 58 , 59 , 60 , 61 ] in this photocatalytic reaction and confirming that ˙OH was the major active species, as shown in Scheme 2 .…”

A Review on Development of Carbon-Based Nanomaterials for Energy Storage Devices: Opportunities and Challenges

“…217−219 These attributes facilitate quick ion diffusion and enhance the interaction between the electrode and electrolyte, rendering them exceptionally well-suited for application in SCs. 220 The direct carbonization of ZIF-8 results in nanoporous carbons that exhibit outstanding electrochemical performance and long-term stability. 221 This synthetic method is not just straightforward but also easy to controllable.…”

“…Due to their exceptional characteristics, carbon materials derived from MOFs hold promise as electrodes for SCs . These carbon materials originate from MOFs and are notable for their substantial specific surface areas and pore volumes. − These attributes facilitate quick ion diffusion and enhance the interaction between the electrode and electrolyte, rendering them exceptionally well-suited for application in SCs . The direct carbonization of ZIF-8 results in nanoporous carbons that exhibit outstanding electrochemical performance and long-term stability .…”

FeS2 and WO3 nanoparticles decorated on biochar as a high throughput electrode for supercapacitors

“…Besides, it can be seen that the specific capacitance increases during cycling at the beginning, indicating that an activation procedure of active materials might exist in the charge/discharge process. 64,65 3.8.3. Electrochemical impedance spectroscopy studies.…”