Binary Fluorides 1976
DOI: 10.1007/978-1-4684-6147-3_1
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“…Contrary to the common chemical knowledge, the noble gases, especially xenon, show rich chemistry. In recent years, there has been growing interest in the chemistry of lighter noble gases, which is due in large part to the preparation of various neutral noble-gas molecules in solid noble-gas matrixes. , In particular, the recent discovery of HArF, , HKrF, solvated HXeOH, noble-gas inserted hydrocarbons, and various noble-gas coordinated metal complexes showed that there are fascinating chemical bonding phenomena and reactions to be explored in this field …”
Section: Introductionmentioning
confidence: 99%
“…Contrary to the common chemical knowledge, the noble gases, especially xenon, show rich chemistry. In recent years, there has been growing interest in the chemistry of lighter noble gases, which is due in large part to the preparation of various neutral noble-gas molecules in solid noble-gas matrixes. , In particular, the recent discovery of HArF, , HKrF, solvated HXeOH, noble-gas inserted hydrocarbons, and various noble-gas coordinated metal complexes showed that there are fascinating chemical bonding phenomena and reactions to be explored in this field …”
Section: Introductionmentioning
confidence: 99%
“…11–13 Subsequently, numerous noble gas compounds containing lighter Ng atoms such as NgBeO (Ng = He, Ne, and Ar) have been reported. 13–35 These types of noble gas compounds are termed ‘donor–acceptor type’, where the Ng atom acts as an electron donor. Following the theoretical exploration of the metastable HHeF 36 compound, which was first of its kind, HArF 37 was successfully synthesized and detected experimentally in 2000.…”
Section: Introductionmentioning
confidence: 99%
“…Noble gas chemistry has a relatively short history since 1962, but it has been becoming a fascinating new field for experimental and theoretical study in recent years. Many new types of noble-gas-containing molecules or ions have been experimentally observed or theoretically predicted. For example, a large variety of HNgY (Ng = noble gas atom, Y = electronegative atoms or groups) type molecules, FNgCCH, and FNgCN , have been made by Räsänen, Khriachtchev, and co-workers, noble-gas-coordinated transition-metal complexes such as M­(CO) 5 Ng have been studied by Perutz and Turner, (η 5 -C 5 R 5 )­M­(CO) 2 Ng have been observed by George and co-workers, AuXe 4 2+ (Sb 2 F 11 – ) 2 have been isolated by Seidel and Seppelt and modeled by Hu and Huang, the noble-gas-complexed actinide compounds CUO·Ng x have been obtained by Andrews and co-workers, the noble gas noble metal halide complex (NgMX) has been observed by Gerry and co-workers, the FNgBO, FNgBNR, F – (NgO) n , NNgO 3 – , and FNgCC – have been predicted by Hu ...…”
Section: Introductionmentioning
confidence: 99%