[BH3C(NO2)3]−: The First Room‐Temperature Stable (Trinitromethyl)borate

Bélanger‐Chabot, Guillaume; Rahm, Martin; Haiges, Ralf

doi:10.1002/ange.201305602

Cited by 12 publications

(2 citation statements)

References 39 publications

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“…As an intriguing example of a compound containing a strong oxidizer (NO 2 group) adjacent to an excellent fuel (CN group),1 nitryl cyanide, NCNO 2 ( 1 ), is a very promising high energy density material (HEDM) by itself and might also be a suitable building block for other energetic compounds. Furthermore, nitryl cyanide might play an important role in atmospheric and interstellar chemistry in view of its simplicity and the known multitude of nitriles in interstellar space 2.…”

Section: Fundamental Vibrational Modes Of Nitryl Cyanidementioning

confidence: 99%

Nitryl Cyanide, NCNO₂

2014

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The elusive nitryl cyanide, NCNO2, has been synthesized and characterized. It was prepared in good yield, isolated by fractional condensation, characterized by NMR and vibrational spectroscopy, and studied by theoretical calculations. Nitryl cyanide holds promise as a high energy density material (HEDM) and might also prove useful as a HEDM building block. The simplicity and inherent stability of nitryl cyanide, together with the known multitude of nitriles in interstellar space, suggest that the compound might also be a potential candidate for observations in atmospheric and interstellar chemistry.

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Section: Fundamental Vibrational Modes Of Nitryl Cyanidementioning

confidence: 99%

Nitryl Cyanide, NCNO₂

2014

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“…Mit der Synthese des Anions [(O2N)3CBH3]— gelang die Darstellung des ersten bei Raumtemperatur stabilen (Trinitromethyl)borats. Die Na+‐, Ph4P+‐ und [Ph3PNPPh3]+‐Salze sind gegenüber Schlag und Reibung stabil, verpuffen aber in der Flamme eines Bunsenbrenners 18…”

Section: Chemie Der Gruppe 13unclassified

Anorganische Chemie 2013

Fischer

Welgand²

2014

Nachr Chem

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Hauptgruppenelemente: Carbene und ihre Homologen sowie die Suche nach dem Außergewöhnlichen — seien es bislang unbekannte Strukturmotive oder Bindungsverhältnisse. Koordinationschemie: Metall‐Metall‐Mehrfachbindungen zwischen zwei unterschiedlichen 3d‐Metallen; Funktion der Arrangements in der supramolekularen Chemie. Bioanorganik: Umsetzung der “kleinen Teilchen” H2, O2, N2 und e− und Einsatz anorganischer Verbindungen für die Pharmazie.

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Ammonia–(Dinitramido)boranes: High‐Energy‐Density Materials

2015

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Two ammonia–(dinitramido)boranes were synthesized by the reaction of dinitroamine with ammonia–borane. These compounds are the first reported examples of (dinitramido)boranes. Ammonia–mono(dinitramido)borane is a perfectly oxygen‐balanced high‐energy‐density material (HEDM) composed of an ammonia–BH2 fuel group and a strongly oxidizing dinitramido ligand. Although it is thermally not stable enough for practical applications, its predicted specific impulse as a solid rocket propellant would be 333 s. Its predicted performance as an explosive matches that of pentaerythtritol tetranitrate (PETN) and significantly exceeds that of trinitrotoluene (TNT). Its structure was established by X‐ray crystallography and vibrational and multinuclear NMR spectroscopy. Additionally, the over‐oxidized ammoniabis(dinitramido)borane was detected by NMR spectroscopy.

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[BH₃C(NO₂)₃]⁻: The First Room‐Temperature Stable (Trinitromethyl)borate

Cited by 12 publications

References 39 publications

Nitryl Cyanide, NCNO₂

Nitryl Cyanide, NCNO₂

Anorganische Chemie 2013

Ammonia–(Dinitramido)boranes: High‐Energy‐Density Materials

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[BH3C(NO2)3]−: The First Room‐Temperature Stable (Trinitromethyl)borate

Cited by 12 publications

References 39 publications

Nitryl Cyanide, NCNO2

Nitryl Cyanide, NCNO2

Anorganische Chemie 2013

Ammonia–(Dinitramido)boranes: High‐Energy‐Density Materials

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[BH₃C(NO₂)₃]⁻: The First Room‐Temperature Stable (Trinitromethyl)borate

Nitryl Cyanide, NCNO₂

Nitryl Cyanide, NCNO₂