Beyond the Active Site: Mechanistic Investigations of the Role of the Secondary Coordination Sphere and Beyond on Multi-Electron Electrocatalytic Reactions and Their Relations Between Kinetics and Thermodynamics
Abstract:<p>The development of an electrocatalyst with a rapid
turnover frequency, low overpotential and long-term stability is highly desired
for fuel-forming reactions, such as water splitting and CO<sub>2</sub>
reduction. The findings of the scaling relationships between the catalytic rate
and thermodynamic parameters over a wide range of electrocatalysts in
homogeneous and heterogeneous systems provide useful guidelines and predictions
for designing better catalysts for those redox reactions. Howe… Show more
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