Bestimmung der Dissoziationsenergien des Iminoradikals aus Daten der Prädissoziation seines (c<sup>1</sup> Π)‐Zustandes

Zetzsch, Cornelius

doi:10.1002/bbpc.197800133

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1981

1993

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Cited by 12 publications

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Formation and Fate of NH(X³Σ⁻) in the Pulsed Vacuum UV Photolysis of NH₃

Zetzsch

Stuhl

1981

Ber Bunsenges Phys Chem

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The formation of NH(X3Σ‐) from the pulsed vacuum uv photolysis (λ > 105 nm) of NH3 was investigated. Using resonance fluorescence detection the kinetics of NH was studied at room temperature. NH could be observed for up to 2 s; the efficiency of removal of NH by collisions with the walls of the reactor is estimated to be of the order of 10−4. A reaction of NH with its parent molecule NH3 or with N2 was not detected. Upper limits for the rate constants of the reactions .

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